有机物A、B、C、D、E、F的转化关系如下： 已知：①A是芳香族化合物，其苯环上有2个对位取代基，均不含支 芳香族化合物A有如下图的转化关系： 已知D能与NaOH溶液...
\u67d0\u82b3\u9999\u65cf\u5316\u5408\u7269A\u7684\u5206\u5b50\u5f0f\u4e3aC 8 H 9 OBr\uff0c\u5176\u82ef\u73af\u4e0a\u7684\u4e00\u6c2f\u4ee3\u7269\u53ea\u6709\u4e24\u79cd\u3002A\u3001B\u3001C\u3001D\u3001E\u3001F\u3001G\u4e03\u79cd\u7269\u8d28\u7684\u8f6c\uff081\uff09 \uff082\uff09\u7f9f\u57fa\u3001\u7fa7\u57fa\uff083\uff09 \uff084\uff09\u916f\u5316\u53cd\u5e94\uff08\u6216\u53d6\u4ee3\u53cd\u5e94\uff09 \uff085\uff09\u5148\u53d6\u5c11\u91cf\u52a0\u5165\u8db3\u91cf\u94f6\u6c28\u6eb6\u6db2\uff0c\u6c34\u6d74\u52a0\u70ed\uff0c\u518d\u53d6\u5c11\u91cf\u53cd\u5e94\u540e\u7684\u6eb6\u6db2\uff08\u9178\u5316\uff09\uff0c\u6ef4\u5165KMnO 4 \u9178\u6027\u6eb6\u6db2\uff0c\u82e5\u892a\u8272\u5219\u8bc1\u660e\u542b\u6709\u53cc\u952e \u7531A\u53ef\u50ac\u5316\u6c27\u5316\u4e3aB\uff0cB\u53ef\u53d1\u751f\u94f6\u955c\u53cd\u5e94\u53ef\u77e5A\u4e2d\u5fc5\u7136\u542b\u6709\u2014CH 2 OH\u57fa\u56e2\uff0c\u53c8\u56e0\u5176\u82ef\u73af\u4e0a\u7684\u4e00\u6c2f\u4ee3\u7269\u53ea\u6709\u4e24\u79cd\uff0c\u53ef\u63a8\u77e5\u82ef\u73af\u4e0a\u4e3a\u5bf9\u4f4d\u53d6\u4ee3\u3002\u7ed3\u5408A\u7684\u5206\u5b50\u5f0f\u4e3aC 8 H 9 OBr\uff0c\u5373A\u9664\u82ef\u73af\uff08C 6 H 4 \uff09\u3001\u2014CH 2 OH\u5916\uff0c\u53ea\u80fd\u4e3a\u2014CH 2 Br\uff0c\u5373\uff21\u4e3a\uff1a \uff085\uff09 CH 3 (CH 2 ) 5 CH\uff1dCH(CH 2 ) 9 CHO\u4e2d\u7684\u78b3\u78b3\u53cc\u952e\u53ca\u919b\u57fa\u5747\u6613\u88ab\u6c27\u5316\uff0c\u6240\u4ee5\u8981\u5148\u5c06\u919b\u57fa\u6c27\u5316\u540e\u518d\u6765\u6c27\u5316\u78b3\u78b3\u53cc\u952e\u3002
C\u80fd\u53d1\u751f\u52a0\u805a\u53cd\u5e94\uff0c\u5e94\u542b\u6709C=C\uff0c\u4e3aB\u548cCH 3 OH\u916f\u5316\u53cd\u5e94\u751f\u6210\uff0c\u7ed3\u5408\u9ad8\u805a\u7269\u7684\u5206\u5b50\u5f0f\u53ef\u77e5B\u5e94\u4e3aCH 2 =CHCOOH\uff0cC\u4e3aCH 2 =CHCOOCH 3 \uff0c\u5219D\u5e94\u542b-OH\uff0c\u80fd\u4e0eNaOH\u6eb6\u6db2\u53cd\u5e94\uff0c\u5e94\u542b\u6709\u915a\u7f9f\u57fa\uff0cE\u8f6c\u5316\u4e3aF\u65f6\uff0c\u4ea7\u7269\u53ea\u6709\u4e00\u79cd\u7ed3\u6784\uff0c\u4e14\u80fd\u4f7f\u6eb4\u7684\u56db\u6c2f\u5316\u78b3\u6eb6\u6db2\u892a\u8272\uff0c\u8bf4\u660eF\u4e2d\u542b\u6709C=C\uff0c\u4e14E\u7ed3\u6784\u5bf9\u79f0\uff0c\u5219F\u4e3a \uff0cE\u5e94\u4e3a \uff0cD\u4e3a \uff0c\u5219A\u4e3a \uff0c\uff081\uff09D\u4e3a \uff0c\u542b\u6709\u915a\u7f9f\u57fa\uff0c\u6545\u7b54\u6848\u4e3a\uff1a\uff08\u915a\uff09\u7f9f\u57fa\uff1b\uff082\uff09B\u4e3aCH 2 =CHCOOH\uff0c\u5206\u5b50\u5f0f\u4e3aC 3 H 4 O 2 \uff0c\u6545\u7b54\u6848\u4e3a\uff1aC 3 H 4 O 2 \uff1b\uff083\uff09\u7531\u4ee5\u4e0a\u5206\u6790\u53ef\u77e5A\u4e3a \uff0cF\u4e3a \uff0c\u6545\u7b54\u6848\u4e3a\uff1a \uff1b \uff1b\uff084\uff09B\u4e3aCH 2 =CHCOOH\uff0c\u4e0e\u7532\u9187\u53d1\u751f\u916f\u5316\u53cd\u5e94\uff0c\u4e5f\u4e3a\u53d6\u4ee3\u53cd\u5e94\uff0c\u53cd\u5e94\u7684\u65b9\u7a0b\u5f0f\u4e3aCH 2 =CHCOOH+CH 3 OH \u6d53\u786b\u9178 \u25b3 CH 2 =CHCOOCH 3 +H 2 O\uff0c \u5728\u6d53\u786b\u9178\u4f5c\u7528\u4e0b\u53d1\u751f\u6d88\u53bb\u53cd\u5e94\uff0c\u53cd\u5e94\u7684\u65b9\u7a0b\u5f0f\u4e3a \uff0c\u6545\u7b54\u6848\u4e3a\uff1aCH 2 =CHCOOH+CH 3 OH \u6d53\u786b\u9178 \u25b3 CH 2 =CHCOOCH 3 +H 2 O\uff1b\u53d6\u4ee3\uff1b \uff1b\u6d88\u53bb\uff1b\uff085\uff09A\u7684\u540c\u5206\u5f02\u6784\u4f53\u4e2d\uff1a\u2460\u82ef\u73af\u542b\u6709\u7684\u4e8c\u53d6\u4ee3\u7ed3\u6784\u5904\u4e8e\u5bf9\u4f4d\uff1b\u2461\u9047FeCl 2 \u6eb6\u6db2\u4e0d\u53d8\u8272\uff0c\u8bf4\u660e\u4e0d\u542b\u6709\u915a\u7f9f\u57fa\uff0c\u2462\u80fd\u53d1\u751f\u94f6\u955c\uff0c\u8bf4\u660e\u542b\u6709-CHO\uff0c\u5219\u5bf9\u5e94\u7684\u7ed3\u6784\u53ef\u80fd\u6709\uff1a \uff0c\u6545\u7b54\u6848\u4e3a\uff1a \uff0e
| （1） 3 +3Br 2 →2HBr+ （2）① （4） +NaHCO 3 →H 2 O+CO 2 + 绛旓細鏄撴兂鍒板伐涓氫笂鐢ㄦ帴瑙︽硶鍒剁～閰革紝鍒橠涓篠O2锛孍涓篠O3锛涳紙2锛B鏄⒈鎬ф皵浣撴槗鎯冲埌鏄疦H3锛屽垯E鏄疦O2锛孉涓篘H4Cl锛孋涓篐Cl锛涳紙3锛塁鏄粍缁胯壊姘斾綋鍗曡川锛屽簲涓篊l2锛孉鏄棩甯哥敓娲讳腑鏈甯歌鐨勭墿璐紝鍒橞涓篘a,E涓篘a2O2锛孉涓篘aCl锛涳紙4锛堿鏄┖闂存瀯鍨嬩负姝ｅ洓闈綋鐨鏈夋満鐗搴斾负CH4锛屽垯B涓C锛孋涓篐2锛孌涓篊O銆 绛旓細鏍规嵁A鈫B+C锛堟按瑙ｅ弽搴旓級鍙互鍒ゆ柇A銆丅銆丆鍒嗗埆鏄叝銆佺晶閰稿拰閱囷紝涓旂敱锛1锛夊彲浠ョ‘瀹欱鍜孋鐨勭粨鏋勫垎鍒负锛圕H3锛2CHCOOH鍜岋紙CH3锛2CHCH2OH锛屽垯D涓 锛圕H3锛2C=CH2锛岀敱D鍒癊鏄彇浠ｅ弽搴锛孍涓猴紝E鍙戠敓姘磋В寰楀埌閱F锛G涓洪啗涓斿惈鏈夊弻閿紝鍙互鍐欏嚭鍏剁粨鏋勪负CH2=C锛圕H3锛-CHO锛屽彂鐢熷弽搴斺懄寰楀埌缇ч吀H涓篊H2=C锛... 绛旓細鐢E鐨勭粨鏋勶紝鍙帹鐭锛孊涓猴紝缁撳悎A鐨勫垎瀛愬紡C12H16O4鍙奀銆丏杞寲涓F鐨鍙嶅簲鏉′欢锛屽彲鎺ㄧ煡C涓轰箼閰锛孌涓轰箼閱囷紝G涓轰箼閱锛孎涓轰箼閰镐箼閰紱鐢BCD鐨勭粨鏋勶紝缁撳悎A鐨勫垎瀛愬紡鍙夾杞寲涓築CD鐨勫弽搴旀潯浠讹紝鍙帹鍑篈涓猴紝锛1锛夊弽搴斺憽涓轰箼閰镐笌涔欓唶鐨勯叝鍖栧弽搴旓紝涔熶负鍙栦唬鍙嶅簲锛屾晠绛旀涓猴細鍙栦唬锛堥叝鍖栵級鍙嶅簲锛涳紙2锛塂涓轰箼閱... 绛旓細鏍规嵁A鈫B+C鍙嶅簲缁撳悎鏈夋満鐗鍒嗗瓙寮忓彲鐭ワ紝搴旀槸鍙戠敓閰殑姘磋В鍙嶅簲锛屽彲浠ュ垽鏂瑼銆丅銆丆鍒嗗埆鏄叝銆佺晶閰稿拰閱囷紝鐢憋紙1锛変腑B鍜孋鍧囦负鏈夋敮閾剧殑鏈夋満鍖栧悎鐗╋紝鍒機鍦ㄦ祿纭吀浣滅敤涓嬪姞鐑弽搴斿彧鑳界敓鎴愪竴绉嶇儻鐑D锛鍙互纭畾B鍜C鐨缁撴瀯鍒嗗埆涓猴紙CH3锛2CHCOOH鍜岋紙CH3锛2CHCH2OH锛屽垯D涓猴紙CH3锛2C=CH2锛岀敱D鍒癊鏄彇浠ｅ弽搴... 绛旓細B鍦ㄦ祿纭吀鍔犵儹鏉′欢涓嬬敓鎴E锛鐢盓鐨勭粨鏋勫彲鐭锛孊鍙戠敓閰寲鍙嶅簲鐢熸垚E锛屾晠B涓猴紟D鐨勫垎瀛愬紡涓篊2H6O锛屼竴瀹氭潯浠朵笅鍙互鐢熸垚C2H4锛屾晠D涓篊H3CH2OH锛孍涓篊H2=CH2锛C涓嶤H3CH2OH鍦ㄦ祿纭吀銆佸姞鐑潯浠朵笅鐢熸垚F锛岀粨鍚F鐨鍒嗗瓙寮廋4H8O2鍙煡锛岀敓鎴怓鐨勫弽搴斾负閰寲鍙嶅簲锛屾晠C涓篊H3COOH锛孎涓篊H3COOCH2CH3锛孉鍦ㄦ阿姘у寲閽犳按婧舵恫銆... 绛旓細B鍦ㄦ祿纭吀銆佸姞鐑潯浠朵笅鍙嶅簲鐢熸垚閰紝鏍规嵁E鐨勭粨鏋勭畝寮忕煡B涓惈鏈夌晶鍩哄拰缇熷熀锛屽叾缁撴瀯绠寮忎负锛锛孌鍦ㄦ祿纭吀銆170鈩冧笅鍙嶅簲鐢熸垚涔欑儻锛岀粨鍚圖鐨勫垎瀛愬紡鐭鏄箼閱锛孋鍜屼箼閱囧湪娴撶～閰搞佸姞鐑潯浠朵笅鍙戠敓閰寲鍙嶅簲鐢熸垚F锛岀粨鍚F鐨鍒嗗瓙寮忕煡锛孋鐨勭粨鏋勭畝寮忎负锛欳H3COOH锛孊鍜孋銆丏鍙戠敓閰寲鍙嶅簲鐢熸垚A锛鍒橝鐨勭粨鏋勭畝寮忎负锛氾紟... 绛旓細o锛屼竴瀹氭潯浠朵笅鍙互鐢熸垚c 2 h 4 锛屾晠d涓篶h 3 ch 2 oh锛宔涓篶h 2 =ch 2 锛c涓巆h 3 ch 2 oh鍦ㄦ祿纭吀銆佸姞鐑潯浠朵笅鐢熸垚f锛岀粨鍚f鐨鍒嗗瓙寮廲4h 8 o 2 鍙煡锛岀敓鎴恌鐨勫弽搴斾负閰寲鍙嶅簲锛屾晠c涓篶h 3 cooh锛宖涓篶h 3 cooch 2 ch 3 锛宎鍦ㄦ阿姘у寲閽犳按婧舵恫銆佸姞鐑潯浠朵笅鍙戠敓姘磋В鍙嶅簲锛岄吀鍖栧緱鍒b... 绛旓細鏍规嵁鍙嶅簲鈶＄殑鐢熸垚鐗╁彲鐭锛孊鐨缁撴瀯绠寮忓彲鐭 銆侫姘磋В鐢熸垚BCD锛鎵浠A鐨缁撴瀯绠寮忎负 銆傦紙1锛塂鏄箼閱囥傦紙2锛夊弽搴斺憿鏄叝鍖栧弽搴旓紝鏂圭▼寮忎负 锛3锛夋牴鎹瓸鐨勭粨鏋勭畝寮忓彲鐭ワ紝B涓惈鏈夌殑瀹樿兘鍥㈡槸缇熷熀鍜岀晶鍩恒傦紙4锛夋牴鎹潯浠跺彲鐭ワ紝绗﹀悎鏉′欢鐨勫悓鍒嗗紓鏋勪綋鏄叡璁℃湁3绉嶃 锛5锛夎冩煡鏈夋満鐗╃殑鍚堟垚锛屼竴鑸墠鏈夐嗘帹... 绛旓細(2)鍙嶅簲鈶㈡槸閰寲鍙嶅簲CH 3 COOH锛婥H 3 CH 2 OH CH 3 COOC 2 H 5 锛婬 2 O銆(3)E鐨勫垎瀛愬紡鏄C 9 H 8 O 2 锛孍鍔犱笂涓涓按鍒嗗瓙涓B锛鍒橞涓篊 9 H 10 O 3 銆(4)鍙嶅簲鈶犳槸姘磋В鍙嶅簲锛孊涓庝箼閰稿拰涔欓唶缁撳悎涓洪叝锛屽嵆涓篈 锛5锛夋湁3涓紝鍒嗗埆鏄細 銆 銆 锛6锛夊埗鑱氫箼鐑細 鎴... 绛旓細G鏄箼鐑紝涔欓唶鍙戠敓娑堝幓鍙嶅簲鐢熸垚涔欑儻锛岀粨鍚圖鐨勫垎瀛愬紡鐭锛孌鏄箼閱囷紱鍦ㄦ祿纭吀浣滃偓鍖栧墏銆佸姞鐑潯浠朵笅锛孊鍙戠敓閰寲鍙嶅簲鐢熸垚E锛鏍规嵁E鐨勭粨鏋勭畝寮忕煡锛孊涓惈鏈夌晶鍩哄拰閱囩緹鍩猴紝鍏剁粨鏋勭畝寮忎负锛氾紝鍦ㄦ祿纭吀浣滃偓鍖栧墏銆佸姞鐑潯浠朵笅锛孋鍜屼箼閱囧彂鐢熼叝鍖栧弽搴旂敓鎴怓锛屾牴鎹F鐨鍒嗗瓙寮忕煡锛孋鏄箼閰革紝鍒橝鏄BCD鍙戠敓閰寲鍙嶅簲鐢熸垚鐨... 本站交流只代表网友个人观点，与本站立场无关 |
