A～J均为有机化合物，它们之间的转化如下图所示 实验表明： ① D既能发生银镜反应，又能与
A\uff5eJ\u5747\u4e3a\u6709\u673a\u5316\u5408\u7269\uff0c\u5b83\u4eec\u4e4b\u95f4\u7684\u8f6c\u5316\u5982\u56fe\u6240\u793a\uff1a\u5b9e\u9a8c\u8868\u660e\uff1a\u2460D\u65e2\u80fd\u53d1\u751f\u94f6\u955c\u53cd\u5e94\uff0c\u53c8\u80fd\u4e0e\u91d1\u5c5e\u94a0\u53cd\u5e94\u653e\u51fa\u6c22\u4f9d\u636e\u9898\u7ed9\u4fe1\u606f\u2460\u2461\uff0c\u53ef\u63a8\u77e5\uff0cCH2=CH-CH=CH2\u4e0eBr2\u53d1\u751f\u7684\u662f1\uff0c4-\u52a0\u6210\uff0cA\u4e3aBrCH2CH=CHCH2Br\uff0c\u4f9d\u6b21\u53ef\u5f97B\u4e3aHOCH2CH=CHCH2OH\uff0cC\u4e3aHOCH2CH2CH2CH2OH\uff0cD\u4e3aHOCH2CH2CH2CHO\uff0cE\u4e3aHOCH2CH2CH2COOH\uff0cF\u4e3a\uff0e\u518d\u5206\u6790\u53e6\u4e00\u6761\u7ebf\uff0cB\u2192G\u5e94\u8be5\u662f\u5206\u5b50\u5185\u6210\u919a\uff0cG\u4e3a\uff1bG\u2192H\u5e94\u8be5\u662fG\u4e0eHClO\u53d1\u751f\u52a0\u6210\u53cd\u5e94\uff0cH\u5e94\u8be5\u4e3a\uff1bH\u2192I\u662f\uff1a2+Ca\uff08OH\uff092=2+CaCl2+2H2O\uff1bI\u2192J\u662f\u919a\u7684\u5f00\u73af\uff0c\u4e94\u5143\u73af\u76f8\u5bf9\u4e8e\u4e09\u5143\u73af\u7a33\u5b9a\uff0c\u56e0\u6b64\u53cd\u5e94\u4e3a\uff1a\uff0e\uff081\uff09\u7531\u4e0a\u8ff0\u5206\u6790\u53ef\u77e5\uff0cA\u4e3aBrCH2CH=CHCH2Br\uff1bA\u53d1\u751f\u53d6\u4ee3\u53cd\u5e94\u751f\u6210B\u4e3aHOCH2CH=CHCH2OH\uff0c\u6545\u7b54\u6848\u4e3a\uff1aBrCH2CH=CHCH2Br\uff1b\u53d6\u4ee3\u53cd\u5e94\uff1b\uff082\uff09\u7531\u4e0a\u8ff0\u5206\u6790\u53ef\u77e5\uff0cD\u7684\u7ed3\u6784\u7b80\u5f0fHOCH2CH2CH2CHO\uff0c\u6545\u7b54\u6848\u4e3a\uff1aHOCH2CH2CH2CHO\uff1b\uff083\uff09E\u4e3aHOCH2CH2CH2COOH\uff0cF\u4e3a\uff0cE\u53d1\u751f\u5206\u5b50\u5185\u916f\u5316\u53cd\u5e94\u751f\u6210F\uff0c\u53cd\u5e94\u65b9\u7a0b\u5f0f\u4e3aHOCH2CH2CH2COOH\u6d53H2SO4\u25b3+H2O\uff0eE\u4e2d\u7684\u5b98\u80fd\u56e2\u6709\u7f9f\u57fa\u3001\u7fa7\u57fa\uff0e\u4e0eE\u5177\u6709\u76f8\u540c\u5b98\u80fd\u56e2\u7684E\u7684\u540c\u5206\u5f02\u6784\u4f53\u8fd8\u6709 \uff0c\u6545\u7b54\u6848\u4e3a\uff1aHOCH2CH2CH2COOH\u6d53H2SO4\u25b3+H2O\uff1b\u7f9f\u57fa\u3001\u7fa7\u57fa\uff1b\uff1b\uff084\uff09\u7531\u4e0a\u8ff0\u5206\u6790\u53ef\u77e5\uff0cG\u7684\u7ed3\u6784\u7b80\u5f0f\u4e3a\uff0c\u6545\u7b54\u6848\u4e3a\uff1a\uff1b\uff085\uff09I\u2192J\u662f\u919a\u7684\u5f00\u73af\uff0c\u4e94\u5143\u73af\u76f8\u5bf9\u4e8e\u4e09\u5143\u73af\u7a33\u5b9a\uff0c\u53cd\u5e94\u65b9\u7a0b\u5f0f\uff0c\u6545\u7b54\u6848\u4e3a\uff1a\uff0e
D\u65e2\u80fd\u53d1\u751f\u94f6\u955c\u53cd\u5e94\uff0c\u53c8\u80fd\u4e0e\u91d1\u5c5e\u94a0\u53cd\u5e94\u653e\u51fa\u6c22\u6c14\uff0c\u8bf4\u660eD\u4e2d\u542b\u6709\u919b\u57fa\u548c\u9187\u7f9f\u57fa\uff0c\u7ed3\u5408\u636e\u9898\u7ed9\u4fe1\u606f\u2460\u53ef\u63a8\u77e5\uff0cCH 2 =CH-CH=CH 2 \u4e0eBr 2 \u53d1\u751f\u7684\u662f1\uff0c4-\u52a0\u6210\uff0c\u6545A\u4e3aBrCH 2 CH=CHCH 2 Br\uff0c\u4f9d\u6b21\u53ef\u5f97B\u4e3aHOCH 2 CH=CHCH 2 OH\uff0cC\u4e3aHOCH 2 CH 2 CH 2 CH 2 OH\uff0cD\u4e3aHOCH 2 CH 2 CH 2 CHO\uff0cE\u4e3aHOCH 2 CH 2 CH 2 COOH\uff0cF\u4e0d\u80fd\u4f7f\u6eb4\u6c34\u892a\u8272\uff0c\u6240\u4ee5F\u4e3a \uff1b\u518d\u5206\u6790\u53e6\u4e00\u6761\u7ebf\uff0cG\u80fd\u4f7f\u6eb4\u7684\u56db\u6c2f\u5316\u78b3\u6eb6\u6db2\u892a\u8272\uff0c\u8bf4\u660eG\u4e2d\u542b\u6709\u78b3\u78b3\u53cc\u952e\uff0c\u6839\u636eB\u548cG\u7684\u5206\u5b50\u5f0f\u77e5\uff0cB\u2192G\u5e94\u8be5\u662f\u5206\u5b50\u5185\u6210\u919a\uff0cG\u4e3a \uff0cG\u2192H\uff0c\u6839\u636eG\u548cH\u7684\u5206\u5b50\u5f0f\u7ed3\u5408\u9898\u7ed9\u4fe1\u606f\u77e5\uff0cH\u5e94\u8be5\u4e3a \uff0e\uff081\uff09\u7531\u4e0a\u8ff0\u5206\u6790\u53ef\u77e5\uff0cA\u4e3aBrCH 2 CH=CHCH 2 Br\uff0cA\u53d1\u751f\u53d6\u4ee3\u53cd\u5e94\uff08\u6216\u6c34\u89e3\u53cd\u5e94\uff09\u751f\u6210B\u4e3aHOCH 2 CH=CHCH 2 OH\uff0c\u6545\u7b54\u6848\u4e3a\uff1aBrCH 2 CH=CHCH 2 Br\uff1b\u53d6\u4ee3\u53cd\u5e94\uff08\u6216\u6c34\u89e3\u53cd\u5e94\uff09\uff1b\uff082\uff09\u7531\u4e0a\u8ff0\u5206\u6790\u53ef\u77e5\uff0cD\u7684\u7ed3\u6784\u7b80\u5f0fHOCH 2 CH 2 CH 2 CHO\uff0c\u6545\u7b54\u6848\u4e3a\uff1aHOCH 2 CH 2 CH 2 CHO\uff1b\uff083\uff09E\u4e3aHOCH 2 CH 2 CH 2 COOH\uff0cF\u4e3a \uff0cE\u53d1\u751f\u5206\u5b50\u5185\u916f\u5316\u53cd\u5e94\u751f\u6210F\uff0c \uff0c\u4e0eE\u5177\u6709\u76f8\u540c\u5b98\u80fd\u56e2\u7684E\u7684\u540c\u5206\u5f02\u6784\u4f53\u8fd8\u6709 \uff0c\u6545\u7b54\u6848\u4e3a\uff1a \uff1b \uff1b\uff084\uff09\u7531\u4e0a\u8ff0\u5206\u6790\u53ef\u77e5\uff0cG\u7684\u7ed3\u6784\u7b80\u5f0f\u4e3a \uff0c\u6545\u7b54\u6848\u4e3a\uff1a \uff1b\uff085\uff09G\u4e3a \uff0cH\u5e94\u8be5\u4e3a \uff0cG\u548c1\u30013-\u4e01\u4e8c\u70ef\u53d1\u751f\u52a0\u6210\u53cd\u5e94\u751f\u6210H\uff0c\u53cd\u5e94\u65b9\u7a0b\u5f0f\u4e3a\uff1a +CH 2 =CHCH=CH 2 \u25b3 \uff0c\u6545\u7b54\u6848\u4e3a\uff1a +CH 2 =CHCH=CH 2 \u25b3 \uff0e
| （1）BrCH 2 CH＝CHCH 2 Br ；取代（或水解） |
| （2） （3） ； 羧基、羟基； （任意两个） （4） （5） |
绛旓細A銆丄l B銆丗e2O3 C銆丄l2O3 D銆丗e E銆丄lCl3 F銆丯aAlO2 G銆丗eCl2 H銆丗e(OH)2 I銆丗e(OH)3 J銆丗eCl3
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绛旓細H鏄竴绉嶇孩鑹插浐浣锛孞鐨勬憾娑插憟榛勮壊锛屽彲鐭鏄搧鐨勭洂婧舵恫锛屽垯H鏄哀鍖栭搧锛屾哀鍖栭搧鍜孖鍙嶅簲浜х敓閾佺洂鍜屾按锛屽洜姝鏄吀锛屽鐩愰吀锛屽垯J鏄隘鍖栭搧锛孋鏄按锛A鏄竴绉嶆恫浣擄紝鍜孊浣滅敤浜х敓C-姘村拰D 涓擝淇濇寔涓嶅彉锛屽洜姝鏄繃姘у寲姘紝B鏄簩姘у寲閿帮紝D鏄哀姘旓紝姘ф皵鍜孍鍙嶅簲浜х敓姘村拰G锛孏鏄哀鍖栭搧鍜岀⒊鍙嶅簲浜х敓鐨勪簩姘у寲纰筹紝...
绛旓細A銆丏涓洪噾灞炲崟璐紝B鏄竴绉嶇孩妫曡壊鍥轰綋锛屽垯A涓嶣鐨勫弽搴斾负閾濈儹鍙嶅簲锛屽垯A涓Al锛孊涓篎e2O3锛孋鑳戒笌閰稿拰纰卞弽搴旓紝鎵浠涓篈l2O3锛孌涓篎e锛岀粨鍚堣浆鍖栧叧绯诲彲鐭ワ紝E涓篈lCl3锛孎涓篘aAlO2锛孏涓篎eCl2锛孒涓篎e锛圤H锛2锛孖涓篎e锛圤H锛3锛孞涓FeCl3锛岋紙1锛夌敱涓婅堪鍒嗘瀽鍙煡锛孊涓篎e2O3锛孒涓篎e锛圤H锛2锛孖涓篎e锛圤H...
绛旓細杞寲鍏崇郴涓紝A銆丏涓哄父瑙侀噾灞炲崟璐紝B銆丆涓洪噾灞炴哀鍖鐗╋紝鍙嶅簲鏉′欢鏄珮娓╄繘琛岋紝鍙互鍒ゆ柇涓洪摑鐑弽搴旓紝A涓Al锛孌涓篎e锛孊涓洪搧鐨勬哀鍖栫墿锛孋涓烘哀鍖栭摑锛涚粨鍚圕涓庢阿姘у寲閽犲弽搴旇瘉鏄庝负Al 2 O 3 锛汦涓篈lCl 3 锛汧涓篘aAlO 2 锛涢氳繃杞寲鍏崇郴鍒ゆ柇锛孏涓篎eCl 2 锛汬涓虹櫧鑹叉矇娣Fe锛圤H锛 2 锛孖涓虹孩瑜愯壊娌夋穩Fe锛圤H...
绛旓細A锝濲鍧囦负鏈夋満鍖栧悎鐗,瀹冧滑涔嬮棿鐨勮浆鍖栧涓嬪浘鎵绀: 瀹為獙琛ㄦ槑: 鈶 D鏃㈣兘鍙戠敓閾堕暅鍙嶅簲,鍙堣兘涓庨噾灞為挔鍙嶅簲鏀惧嚭姘㈡皵: 鈶 鏍哥鍏辨尟姘㈣氨琛ㄦ槑F鍒嗗瓙涓湁涓夌姘,涓斿叾宄伴潰绉箣姣斾负1:1:1; 鈶 G鑳戒娇婧寸殑鍥涙隘鍖栫⒊婧舵恫瑜壊; 鈶 1mol J涓庤冻閲忛噾灞為挔鍙嶅簲鍙斁鍑22.4L姘㈡皵(鏍囧噯鐘跺喌)銆 璇锋牴鎹互涓婁俊鎭洖绛斾笅鍒楅棶棰: (1)...
绛旓細A-J 渚濇鏄細姘皵銆佹阿姘斻佹哀姘斻佸崟璐ㄩ搧銆佹隘鍖栨阿銆佹按銆佺洂閰搞佸洓姘у寲涓夐搧銆佷笁姘寲閾併佷簩姘寲閾併
绛旓細I涓虹孩瑜愯壊鍥轰綋锛屽垯I涓篎e锛圤H锛3锛屽姞鐑垎瑙ｇ敓鎴怋涓篎e2O3锛孖涓庣洂閰稿弽搴旂敓鎴J锛屽垯J涓篎eCl3锛嶥涓嶫鍙嶅簲鐢熸垚G锛孏涓庢阿姘у寲閽犲弽搴旂敓鎴怘锛孒鍦ㄧ┖姘斾腑杞寲涓烘阿姘у寲閾侊紝鍒橦涓篎e锛圤H锛2锛嶢銆丏涓洪噾灞炲崟璐紝D涓篎e锛屽垯G涓篎eCl2锛孉涓嶣鐨勫弽搴旂敓鎴怌涓嶥锛屽垯C涓洪噾灞炴哀鍖鐗╋紝鏃笌姘㈡哀鍖栭挔鍙嶅簲鍙堜笌鐩愰吀鍙嶅簲锛屽垯...
绛旓細A鏄煭鍛ㄦ湡鍏冪礌缁勬垚鐨勫父瑙佹皵浣撳崟璐紝涓旇兘鍜岀煶鐏颁钩鍙嶅簲锛屽垯A鏄疌l2锛屾隘姘斿拰姘㈡哀鍖栭挋鍙嶅簲鐢熸垚姘寲閽欍佹姘吀閽欏拰姘达紝B鏄棩甯哥敓娲诲父瑙侀噾灞烇紝鑳藉拰I鍙嶅簲鐢熸垚E锛孍鑳藉拰C鐨勬按婧舵恫鍙戠敓鍙嶅簲锛屽垯璇ラ噾灞炲簲璇ヤ负鍙樹环閲戝睘锛屾墍浠ユ槸Fe锛孖鏄鍖栧悎鐗╋紝搴旇鏄吀锛孍鏄簹閾佺洂锛岃兘琚姘吀閽欐哀鍖栵紝鍒機鏄疌a锛圕lO锛2锛孌鏄疌aCl2...
绛旓細鐢熸垚鐧借壊绲姸娌夋穩 鍦ㄧ┖姘斾腑鍙樻垚鐏扮豢鑹 鏈鍚庡彉鎴愮孩鑹 FeCl2+2NaOH==Fe锛圤H锛2+2NaCl 4Fe锛圤H锛2+2H20+O2==4Fe(OH)3 2Fe2+ + Cl2==2Fe3+ + 2Cl- Fe3O4 + 8H+==Fe2+ + 2Fe3+ +4H2O
