现有A、B、C、D、E、F五种有机物,它们的转化关系如下图所示(图中部分反应条件及生成物没有全部写出).
\u6709A\u3001B\u3001G\u4e09\u79cd\u6709\u673a\u7269\uff0c\u5b83\u4eec\u5728\u4e00\u5b9a\u6761\u4ef6\u4e0b\uff0c\u90fd\u80fd\u4e0eNaOH\u6eb6\u6db2\u53cd\u5e94\uff0c\u5176\u751f\u6210\u7269\u8fd8\u80fd\u53d1\u751f\u5982\u4e0b\u56fe\u6240\u793a\u7684\u53d8\u5316\u3002A:CH3COONH4\u6216\u8005CH3CONH2
B:CH3COOCH2CH3
C:CH3CHO
D:NH3
E:CH3COONa
F:CH3CH2OH
G:CH3COOH
A-E\u53cd\u5e94
CH3COONH4+NaOH==CH3COONa+NH3+H2O
\u6216\u8005CH3CONH2+NaOH==CH3COONa+NH3
\u7b2c\u4e8c\u6b65
2CH3CHO+2Cu(OH)2==2CH3COOH+Cu2O+2H2O
E\u9047FeCl3\u6eb6\u6db2\u5448\u7d2b\u8272\uff0c\u5e94\u542b\u6709\u915a\u7f9f\u57fa\uff0cG\u80fd\u53d1\u751f\u6d88\u53bb\u53cd\u5e94\uff0c\u6c27\u5316\u53cd\u5e94\uff0c\u5e94\u4e3a\u9187\uff0c\u5219F\u4e3a\u919b\uff0cD\u4e3a\u9178\uff0c\u7ed3\u5408A\u7684\u5206\u5b50\u5f0f\u53ef\u77e5E\u4e3a\uff0cD\u4e3aCH3COOH\uff0cF\u4e3aCH3CHO\uff0cG\u4e3aCH3CH2OH\uff0cH\u4e3aCH2=CH2\uff0c\uff081\uff09\u7531\u4ee5\u4e0a\u5206\u6790\u53ef\u77e5H\u4e3aCH2=CH2\uff0c\u542b\u6709\u7684\u5b98\u80fd\u56e2\u4e3a\u78b3\u78b3\u53cc\u952e\uff0cF\u4e3aCH3CHO\uff0c\u542b\u6709\u7684\u5b98\u80fd\u56e2\u4e3a\u919b\u57fa\uff0c\u6545\u7b54\u6848\u4e3a\uff1a\u78b3\u78b3\u53cc\u952e\uff1b\u919b\u57fa\uff1b\uff082\uff09\u7531\u4ee5\u4e0a\u5206\u6790\u53ef\u77e5E\u4e3a\uff0c\u6545\u7b54\u6848\u4e3a\uff1a\uff1b\uff083\uff09G\u4e3aCH3CH2OH\uff0c\u542b\u6709-OH\uff0c\u53ef\u53d1\u751f\u53d6\u4ee3\u3001\u6c27\u5316\u3001\u6d88\u53bb\u53cd\u5e94\uff0c\u4f46\u4e0d\u80fd\u53d1\u751f\u52a0\u6210\u3001\u52a0\u805a\u53cd\u5e94\uff0c\u6545\u7b54\u6848\u4e3a\uff1aBD\uff1b\uff084\uff09\u6709\u673a\u7269A\u4e3a\u4e59\u9178\u82ef\uff08\u915a\uff09\u916f\uff0c\u5bf9\u5e94\u7684\u4e00\u79cd\u540c\u5206\u5f02\u6784\u4f53X\uff0c\u80fd\u53d1\u751f\u94f6\u955c\u53cd\u5e94\uff0c\u8bf4\u660e\u542b\u6709\u919b\u57fa\uff0c\u4e14\u542b\u6709\u4e0eE\u76f8\u540c\u7684\u5b98\u80fd\u56e2\uff0c\u5e94\u542b\u6709\u915a\u7f9f\u57fa\uff0c\u6709\u4e24\u79cd\u60c5\u51b5\uff0c\u5f53\u82ef\u73af\u4e0a\u67092\u4e2a\u53d6\u4ee3\u57fa\u65f6\uff0c\u4e00\u4e2a\u4e3a-OH\uff0c\u53e6\u4e00\u53d6\u4ee3\u57fa\u4e3a-CH2CHO\uff0c\u7531\u90bb\u3001\u95f4\u3001\u5bf93\u79cd\uff0c\u5f53\u82ef\u73af\u4e0a\u67093\u4e2a\u53d6\u4ee3\u57fa\u65f6\uff0c\u53ef\u4e3a-OH\u3001-CHO\u548c-CH3\uff0c\u517110\u79cd\uff0c\u5219\u4e00\u5171\u670913\u79cd\uff0c\u6545\u7b54\u6848\u4e3a\uff1a13\uff1b\uff085\uff09\u53cd\u5e94\u2462\u4e3a\u4e59\u919b\u7684\u6c27\u5316\u53cd\u5e94\uff0c\u53cd\u5e94\u7684\u65b9\u7a0b\u5f0f\u4e3a2CH3CHO+O2\u50ac\u5316\u52422CH3COOH\uff0c\u53cd\u5e94\u2465\u4e3a\u4e59\u9187\u7684\u6d88\u53bb\u53cd\u5e94\uff0c\u53cd\u5e94\u7684\u65b9\u7a0b\u5f0f\u4e3aCH3CH2OH\u6d53\u786b\u9178170\u2103CH2=CH2+H2O\uff0c\u6545\u7b54\u6848\u4e3a\uff1a2CH3CHO+O2\u50ac\u5316\u52422CH3COOH\uff1bCH3CH2OH\u6d53\u786b\u9178170\u2103CH2=CH2+H2O\uff0e
A在浓硫酸、170℃生成气体D,气体D的相对分子质量为28,且D可以合成常用塑料F,故A为乙醇、D为乙烯、F为聚乙烯,由转化关系可知,D与HBr反应生成C,C为溴乙烷,A氧化生成B,液体B能发生银镜反应,故B为乙醛,乙醛氧化生成E,E能与碳酸氢钠反应,故E为乙酸, (1)由上述分析可知,A为乙醇,结构简式为 CH 3 CH 2 OH, B是乙醛,结构简式为CH 3 CHO, C是溴乙烷,结构简式是CH 3 CH 2 Br, 故答案为:CH 3 CH 2 OH,CH 3 CHO,CH 3 CH 2 Br; (2)C→A是溴乙烷发生消去反应,反应方程式为CH 3 CH 2 Br+NaOH
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