有机化学问题
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环酯
绛旓細鏈夋満鎺ㄦ柇棰橀冧笉寮 鐑-->鍗や唬鐑-->閱-->閱-->閰-->閰 杩欐牱鐨勫彉鍖栵紝鐗瑰埆鏄叝鍖栧弽搴旓紝鏄竴瀹氭湁鐨勩傛墍浠ュ鏋滅湅鍒版祿纭吀鍔犵儹鐨勶紝宸笉澶氬氨鏄叝鍖栧弽搴旓紙杩樻湁鍙兘鏄唶鐨勬秷鍘伙紝浣嗗彲鑳芥т笉澶э級銆傛墍浠ュ彧闇瑕佽浣忎竴浜涚壒寰佸弽搴旓紝灏卞緢蹇兘鎵惧埌绐佺牬鍙ｃ傛湁鏈虹殑閲嶇偣灏辨槸鍐鍖栧鏂圭▼寮忋傛湁鏈烘帹鏂涓ぇ鍗婄殑鍒嗘暟閮芥槸...
绛旓細1銆佷箼閱囧拰姘存秷鑰桸a鐨勬瘮渚嬩笉涓鏍凤紝娉ㄦ剰mol涓鏍凤紝浣嗚川閲忎笉涓鏍凤紝鍔犱笂瀵嗗害锛屾墍浠ヤ綋绉笉涓鏍凤紝鐜板湪缁欎綘鐨勬槸浣撶Н锛岃杞寲涓鸿川閲忓悗鍐嶈浆鍖栦负mol杩涜璁＄畻鍒嗘瀽锛屽惈姘村悗纭疄浜х敓姘㈡皵澶氫簡锛屽洜涓烘按鐨勬懇灏旇川閲忓皬锛屾墍浠ョ瓑浣撶Н鐨勬按鍜屼箼閱囷紝鍚按鎽╁皵澶氫竴浜涖2銆佸簲璇ョ悊瑙ｄ负鍙簰婧讹紝涓嶅姞璇存槑锛屼竴鑸涓鏈夋満鐗╀箣闂存槸...
绛旓細浜茬數鍔犳垚锛岄【鍚嶆濅箟锛岀儻鐑冨弻閿笂鐨勭數瀛愪簯瀵嗗害瓒婂ぇ锛岃秺鍒╀簬鍙嶅簲鍙戠敓锛屽洜姝わ紝鏍规湰鍦ㄤ簬鍒ゆ柇鍙岄敭涓婅繛鎺ョ殑鍘熷瓙鎴栧師瀛愬洟鏄枼鐢靛瓙杩樻槸鍚哥數瀛愩1.涔欑儻CH2=CH2 < 涓欑儻CH2=CHCH3 < 2-涓佺儻CH3CH=CHCH3 涓嶩鍘熷瓙鐩告瘮锛岀兎鍩烘槸鏂ョ數瀛愬熀鍥紝鐑峰熀瓒婂锛屽鍙岄敭鐨勬枼鐢靛瓙鏁堝簲瓒婂ぇ锛屾墍浠ワ紝鐢靛瓙浜戝瘑搴﹁秺澶 2.1-涓佺儻...
绛旓細1銆佷弗鏍煎湴璁诧紝鍙湁閱囧拰閰稿弽搴旀墠鑳藉彨閰寲锛屼絾鍙鏈夌緹鍩哄拰缇у熀灏辫兘鍙嶅簲锛屽彧涓嶈繃鏈変簺涓嶈兘鍙叝鍖栧弽搴斻2銆鏈夋満姘у寲鏉′欢鏈夊緢澶氥傞鍏堬紝鍑犱箮鎵鏈夋湁鏈虹墿閮借兘鐕冪儳锛屾槸姘у寲鍙嶅簲锛屼絾鍦ㄩ珮涓鐩噷鐨勬湁鏈虹墿姘у寲涓嶅寘鎷噧鐑э紙鍚﹀垯灏辩櫧璇翠簡锛岄兘鑳界噧鐑у晩锛夈傛渶甯歌鐨勬哀鍖栵紝姣斿楂橀敯閰搁捑姘у寲CC鍙岄敭锛岄唶鍒伴啗鍒伴吀鐨...
绛旓細瑙ｆ瀽锛8. Ph-NH-NH2 + H3C-C-CH3 鈫 Ph-NH-N=C-CH3 + H2O || | O CH3 9. H3C-CH2-CH=CH2 --锛圔2H6銆丯aOH/H2O2锛夆啋 H3C-CH2-CH2-CH2-OH O - CH2 \ \
绛旓細姝ｈВ锛氬姞閫傞噺姘㈡哀鍖栭挔婧舵恫鍏呭垎鎸崱锛屽皢鑻厷杞寲涓烘槗婧朵簬姘寸殑鑻厷閽狅紝鍒嗘恫銆傝繖鏄洜涓鸿嫰閰氫笌NaOH婧舵恫鍙嶅簲鍚庣敓鎴愮殑鑻厷閽犳槸閽犵洂锛屾槗婧朵簬姘磋岄毦婧朵簬鐢茶嫰锛堢洂绫讳竴鑸毦婧朵簬鏈夋満鐗╋級锛屼粠鑰屽彲鐢ㄥ垎娑叉硶闄ゅ幓銆傦紙8锛変箼閰镐箼閰紙涔欓吀锛夐敊渚婣锛氬姞姘村厖鍒嗘尟鑽★紝鍒嗘恫銆傞敊渚婤锛氬姞涔欓唶鍜屾祿纭吀锛屽姞鐑紝浣夸箼閰稿拰涔欓唶鍙戠敓...
绛旓細CH3C=O(1)O(2)路 --- CH3C=O(2)O(1)路锛岀景鍩哄叡鎸殑缁撴灉浣垮緱鍗曠數瀛愮敱O(2)鍒嗘暎鍒癘(1)锛屼綋绯昏幏寰楃ǔ瀹氳兘銆(闄勫姞璇翠竴鍙ワ紝閭ｄ釜璇存硶涓鐐逛篃涓嶅北瀵紝璇︾粏璧勬枡璇疯Carey楂樼瓑鏈夋満绗簲鐗圥art A锛岀涓夌珷 Section 3.4.3)7.RH = R路 + H路锛岃繖涓弽搴旂殑鍙嶅簲鐒撳氨鏄疌-H閿兘锛屽畠绛変簬鐢熸垚鐨勮嚜鐢卞熀...
绛旓細璁綡鐨勭浉瀵瑰垎瀛愯川閲忎负X 娑堣桸aOH鐨勭墿璐ㄧ殑閲忎负锛0.02L脳0.2mol/L锛0.004mol H 锛嶏紞锛 2NaOH X 2 0.2520g 0.004mol 瑙ｅ緱锛歑锛126 鐢变簬閲岄潰鏈変袱涓晶鍩猴紝涓や釜缇у熀鐨勭浉瀵瑰垎瀛愯川閲忎负:45脳2锛90 鍓╀笅閮ㄥ垎鐨勭浉瀵瑰垎瀛愯川閲忎负锛126锛90锛36锛堝垰濂芥槸涓や釜缁撴櫠姘寸殑鐩稿鍒嗗瓙璐ㄩ噺锛塇鐨勭粨鏋勭畝...
绛旓細鏁呭繀涓虹敳鐑峰拰鍏跺畠涓夎(涔嬩竴鎴栬嫢骞)鐨勬贩鍚堟皵浣撱6. A閫夐」鍙惈鏈変竴涓弻閿殑鐩撮摼鏈夋満鐗╋紝绗﹀悎棰樻剰锛涚敱鍘熷垎瀛愬紡鍙煡搴斾负涓姘唬鑴傜儍(鍚⒊鏁板皬浜6涓嶅彲鑳戒负鍚姵鐑冪粨鏋)锛屼笖姘師瀛愪粎涓轰竴鍏变环鏁呭彲琚阿绛夋晥鏇夸唬鑰屾帹鐭ヤ笉楗卞拰搴︿负2锛屽崟涓弻閿垨鐜潎瑙嗕负涓涓笉楗卞拰搴︼紝鍗曚釜鍙侀敭瑙嗕负涓や釜涓嶉ケ鍜屽害锛屾晠鍙湁A...
绛旓細B姘у寲鍚庡緱涔欓吀涓庝竴鍒嗗瓙閰紝B鏈変簲涓⒊锛岄偅涔堥叜褰撶劧灏辨槸涓欓叜浜嗐侭鍗や唬鐑冩槸娑堝幓浜х墿锛屾墍浠ユ槸鐑儍锛屾哀鍖栨柇瑁傜殑鏄弻閿備篃灏辨槸璇达紝鍏舵哀鍖栦骇鐗╃殑姘у師瀛愬湪鍙岄敭鐨勪袱涓⒊涓娿傛墍浠ワ紝鎶婁箼閰哥殑姘у幓鎺夛紝涓欓叜鐨勬哀鍘绘帀锛岃繛涓婁袱鑰呭幓鎺夋哀鐨勭⒊鍘熷瓙锛屽氨鏄疊浜嗐傚彲鐭ワ紝B鏄2-鐢插熀-2-涓佺儻(杩欑帺鎰忓効鐧惧害涓涓嬭兘寰堟柟渚垮湴...
