2000年一家制药公司首次在网站上悬赏下列化合物的合成路线，悬赏金额为$100000．该化合物的结构如图1：试 跪求：要高一化学几道竞赛题（或试卷） 附答案
2000\u5e74\u4e00\u5bb6\u5236\u836f\u516c\u53f8\u9996\u6b21\u5728\u7f51\u7ad9\u4e0a\u60ac\u8d4f\u4e0b\u5217\u5316\u5408\u7269\u7684\u5408\u6210\u8def\u7ebf\uff0e\u622a\u6b62\u65e5\u671f\u4e3a2002\u5e744\u67081\u65e5\uff0c\u60ac\u8d4f\u91d1\u989d\u4e3a$100\uff0c00\u7531\u9898\u610f\u53ef\u77e5\u5206\u5b50\u4e2d\u6709\u51e0\u79cd\u7c7b\u578b\u7684\u6c22\u539f\u5b50\u5c31\u4f1a\u51fa\u73b0\u51e0\u4e2a\u5cf0\uff0c\u56fe2\u4e2d\u51718\u4e2a\u5cf0\uff0c\u5c5e\u4e8e\u67098\u79cd\u5316\u5b66\u73af\u5883\u4e0d\u540c\u7684\u6c22\u539f\u5b50\uff1b\u5316\u5b66\u73af\u5883\u76f8\u540c\u7684\u6c22\u539f\u5b50\u8d8a\u591a\uff0c\u5cf0\u7ebf\u7684\u5f3a\u5ea6\uff08\u9ad8\u5ea6\uff09\u8d8a\u5927\uff0c\u5316\u5b66\u73af\u5883\u76f8\u540c\u7684\u6c22\u539f\u5b50\u4e3a-CH3\u4e0a\u7684H\uff0c\u51713\u4e2a\uff0c\u8c31\u7ebf\u6700\u4f4e\u8005\u8868\u793a\u67091\u4e2aH\uff0c\u4ecb\u4e8e\u4e24\u8005\u4e4b\u95f4\u4e3a-CH2-\u4e0a\u7684H\uff0c\u5bf9\u6bd4\u7ed3\u6784\u5f0f\uff0c\u8fd9\u4e2a\u70f7\u70c3\u57faCH3CH2-\uff1b\u6545\u7b54\u6848\u4e3a\uff1a8\uff1b3\uff1b1\uff1bCH3CH2-\uff1b
\u4e00\uff0e\u9009\u62e9\u9898\uff08\u672c\u9898\u5305\u62ec10\u5c0f\u9898\uff0c\u6bcf\u5c0f\u98984\u5206\uff0c\u517140\u5206\uff0c\u6bcf\u5c0f\u9898\u53ea\u6709\u4e00\u4e2a\u9009\u9879\u7b26\u5408\u9898\u610f\uff09
1\uff0e\u6211\u56fd\u201c\u795e\u821f5\u53f7\u201d\u5b87\u5b99\u98de\u8239\u7684\u8fd0\u8f7d\u706b\u7bad\u7684\u63a8\u8fdb\u5242\u5f15\u71c3\u540e\u53d1\u751f\u5267\u70c8\u53cd\u5e94\uff0c\u4ea7\u751f\u5927\u91cf\u9ad8\u6e29\u6c14\u4f53\u4ece\u706b\u7bad\u5c3e\u90e8\u55b7\u51fa\u3002\u5f15\u71c3\u540e\u7684\u9ad8\u6e29\u6c14\u4f53\u6210\u5206\u6709CO2\u3001H2O\u3001N2\u3001NO\u7b49\uff0c\u8fd9\u4e9b\u6c14\u4f53\u5747\u4e3a\u65e0\u8272\uff0c\u4f46\u5728\u536b\u661f\u53d1\u5c04\u73b0\u573a\u770b\u5230\u706b\u7bad\u55b7\u5c04\u51fa\u5927\u91cf\u7ea2\u70df\uff0c\u4ea7\u751f\u7ea2\u70df\u7684\u539f\u56e0\u662f
(A) \u9ad8\u6e29\u4e0bN2\u9047\u7a7a\u6c14\u751f\u6210NO2 (B) NO\u9047\u7a7a\u6c14\u751f\u6210NO2
(C) CO2\u4e0eNO\u53cd\u5e94\u751f\u6210NO2 (D) NO\u4e0eH2O\u53cd\u5e94\u751f\u6210NO2
2\uff0e\u4e0b\u5217\u7269\u8d28\u4f7f\u7528\u5408\u7406\u7684\u662f
(A) \u5728\u5236\u73bb\u7483\u7684\u539f\u6599\u4e2d\u518d\u52a0\u5165Co2O3\u5236\u6210\u84dd\u8272\u73bb\u7483(B)\u7528\u52a0\u9176\u6d17\u8863\u7c89\u6d17\u6da4\u6bdb\u6599\u670d\u88c5
(C)\u7528\u7532\u919b\u6eb6\u6db2\u6d78\u6ce1\u6d77\u4ea7\u98df\u54c1(D)\u7528\u915a\u919b\u6811\u8102\u5236\u4f5c\u9ad8\u5f39\u529b\u8fd0\u52a8\u978b
3\uff0e\u5bf9\u76d0\u7c7b\u7269\u8d28\u53ef\u6709\u4e0b\u5217\u5206\u7c7b\uff1a\u5982\u6c2f\u5316\u785d\u9178\u9499[Ca(NO3)Cl]\u662f\u4e00\u79cd\u6df7\u76d0\uff0c\u786b\u9178\u94dd\u94beKAl(SO4)2\u662f\u4e00\u79cd\u590d\u76d0\uff0c\u51b0\u6676\u77f3\uff08\u516d\u6c1f\u5408\u94dd\u9178\u94a0\uff09Na3AlF6\u662f\u4e00\u79cd\u7edc\u76d0\u3002\u5bf9\u4e8e\u7ec4\u6210\u4e3aCaOCl2\u7684\u76d0\u53ef\u5f52\u7c7b\u4e8e
\uff08A\uff09\u6df7\u76d0 \uff08B\uff09\u590d\u76d0 \uff08C\uff09\u7edc\u76d0 \uff08D\uff09\u65e0\u6cd5\u5f52\u5c5e\u4e8e\u4e0a\u8ff0\u7c7b\u522b
4\uff0e\u67d0\u540c\u5b66\u5728\u505a\u82ef\u915a\u7684\u6027\u8d28\u5b9e\u9a8c\u65f6\uff0c\u5c06\u5c11\u91cf\u6eb4\u6c34\u6ef4\u5165\u82ef\u915a\u6eb6\u6db2\u4e2d\uff0c\u7ed3\u679c\u6ca1\u6709\u53d1\u751f\u6c89\u6dc0\u73b0\u8c61\uff0c\u4ed6\u601d\u8003\u4e86\u4e00\u4e0b\uff0c\u53c8\u7ee7\u7eed\u5728\u53cd\u5e94\u6df7\u5408\u6db2\u4e2d\u6ef4\u5165\u8db3\u91cf\u7684\u6c22\u6c27\u5316\u94a0\u6eb6\u6db2\uff0c\u6b64\u65f6\u4ed6\u53d1\u73b0
(A) \u6eb6\u6db2\u4e2d\u4ecd\u65e0\u6c89\u6dc0 (B) \u6eb6\u6db2\u4e2d\u4ea7\u751f\u767d\u8272\u6c89\u6dc0
(C) \u5148\u4ea7\u751f\u6c89\u6dc0\u540e\u6c89\u6dc0\u6eb6\u89e3 (D) \u6eb6\u6db2\u5448\u6a59\u8272
5\uff0e\u9553\u662f1871\u5e74\u4fc4\u56fd\u5316\u5b66\u5bb6\u95e8\u6377\u5217\u592b\u5728\u7f16\u5236\u5143\u7d20\u5468\u671f\u8868\u65f6\u66fe\u9884\u8a00\u7684\u201c\u7c7b\u94dd\u201d\u5143\u7d20\u3002\u9553\u7684\u539f\u5b50\u5e8f\u6570\u4e3a31\uff0c\u5c5e\u2162A\u65cf\u3002\u9553\u7684\u7194\u70b9\u4e3a29.78\u2103,\u6cb8\u70b9\u9ad8\u8fbe2403\u2103\u3002\u9553\u6709\u8fc7\u51b7\u73b0\u8c61\uff08\u5373\u51b7\u81f3\u7194\u70b9\u4e0b\u4e0d\u51dd\u56fa\uff09\uff0c\u5b83\u53ef\u8fc7\u51b7\u5230-120\u2103\u3002\u7531\u6b64\u5224\u65ad\u4e0b\u5217\u6709\u5173\u9553\u7684\u6027\u8d28\u53ca\u5176\u7528\u9014\u7684\u53d9\u8ff0\u4e0d\u6b63\u786e\u7684\u662f
\uff08A\uff09\u9553\u662f\u5236\u9020\u9ad8\u6e29\u6e29\u5ea6\u8ba1\u7684\u4e0a\u4f73\u6750\u6599
(B) \u9553\u80fd\u6eb6\u4e8e\u5f3a\u9178\u548c\u5f3a\u78b1\u4e2d
(C) \u9553\u4e0e\u950c\u3001\u9521\u3001\u94df\u7b49\u91d1\u5c5e\u5236\u6210\u7684\u5408\u91d1\uff0c\u53ef\u7528\u5728\u81ea\u52a8\u6551\u706b\u7684\u6c34\u9f99\u5934\u4e2d
(D) \u8fd1\u5e74\u6765\u9553\u6210\u4e3a\u7535\u5b50\u5de5\u4e1a\u7684\u65b0\u5ba0\uff0c\u5176\u4e3b\u8981\u7528\u9014\u662f\u5236\u9020\u534a\u5bfc\u4f53\u6750\u6599\uff0c\u88ab\u8a89\u4e3a\u201c\u534a\u5bfc\u4f53\u6750\u6599\u7684\u65b0\u7cae\u98df\u201d\uff0c\u8fd9\u662f\u5229\u7528\u4e86\u9553\u7684\u5bfc\u7535\u6027\u4ecb\u4e8e\u5bfc\u4f53\u548c\u7edd\u7f18\u4f53\u4e4b\u95f4\u7684\u6027\u8d28
6\uff0e\u5411\u542b1mol HCl\u548c1mol MgSO4\u7684\u6df7\u5408\u6eb6\u6db2\u4e2d\u52a0\u51651 mol•L-1Ba(OH)2\u6eb6\u6db2\uff0c\u4ea7\u751f\u6c89\u6dc0\u7684\u7269\u8d28\u7684\u91cf\uff08n\uff09\u4e0e\u52a0\u5165Ba(OH)2\u6eb6\u6db2\u4f53\u79ef\uff08V\uff09\u95f4\u7684\u5173\u7cfb\u56fe\u6b63\u786e\u7684\u662f
\uff08A\uff09 \uff08B\uff09 \uff08C\uff09 \uff08D\uff09
7\uff0e\u4e0b\u5217\u79bb\u5b50\u65b9\u7a0b\u5f0f\u6b63\u786e\u7684\u662f
\uff08A\uff09\u5c060.1mol•L-1HCl\u6eb6\u6db2\u6570\u6ef4\u7f13\u7f13\u6ef4\u51651mol•L-1 50mLNa3PO4\u6eb6\u6db2\u4e2d\uff0c\u4e14\u4e0d\u65ad\u6405\u62cc\uff1a
3H+ + PO43-=H3PO4
(B) \u5c061mol•L-1 NaAlO2\u6eb6\u6db2\u548c1.5mol•L-1\u7684HCl\u6eb6\u6db2\u7b49\u4f53\u79ef\u4e92\u76f8\u5747\u5300\u6df7\u5408
6AlO2- + 9H+ + 3H2O = 5Al(OH)3\u2193+ Al3+
(C) \u54111mol•L-1\u660e\u77fe\u6eb6\u6db250mL\u4e2d\u6ef4\u5165\u6570\u6ef40.1mol•L-1Ba(OH)2\u6eb6\u6db2
Al3++2SO42-+2Ba2++3OH-=Al(OH)3\u2193+2BaSO4\u2193
\uff08D\uff09\u5c06\u5c11\u91cfSO2\u6c14\u4f53\u901a\u5165NaClO\u6eb6\u6db2\u4e2d\uff1aSO2+H2O+ ClO-=SO42-+Cl-+2H+
8\uff0e\u7269\u8d28\u7684\u91cf\u6d53\u5ea6\u76f8\u540c\u7684NaCl\u6eb6\u6db2\u548cNaClO\u6eb6\u6db2\u4e2d\uff0c\u4e0b\u5217\u5173\u7cfb\u6b63\u786e\u7684\u662f
\uff08A\uff09NaCl\u6eb6\u6db2\u4e2d\u79bb\u5b50\u7684\u603b\u6d53\u5ea6\u548cNaClO\u6eb6\u6db2\u4e2d\u79bb\u5b50\u7684\u603b\u6d53\u5ea6\u76f8\u7b49
\uff08B\uff09NaCl\u6eb6\u6db2\u4e2d\u79bb\u5b50\u7684\u603b\u6d53\u5ea6\u5927\u4e8eNaClO\u6eb6\u6db2\u4e2d\u79bb\u5b50\u7684\u603b\u6d53\u5ea6
\uff08C\uff09NaCl\u6eb6\u6db2\u4e2d\u79bb\u5b50\u7684\u603b\u6d53\u5ea6\u5c0f\u4e8eNaClO\u6eb6\u6db2\u4e2d\u79bb\u5b50\u7684\u603b\u6d53\u5ea6
\uff08D\uff09NaCl\u6eb6\u6db2\u7684pH\u5927\u4e8eNaClO\u6eb6\u6db2\u7684pH
9\uff0e\u66f2\u9178\u662f\u4e00\u79cd\u975e\u5e38\u6709\u6f5c\u529b\u7684\u98df\u54c1\u6dfb\u52a0\u5242\u3002\u7ecf\u6d4b\u5b9a\u66f2\u9178\u7684\u5206\u5b50\u5f0f\u4e3aC6H6O4\uff0c\u7ed3\u6784\u5f0f\u5982\u53f3\u56fe\u6240\u793a\uff0c\u8bd5\u6839\u636e\u66f2\u9178\u5206\u5b50\u7ed3\u6784\u7279\u70b9\uff0c\u63a8\u6d4b\u66f2\u9178\u4e0d\u53ef\u80fd\u5177\u6709\u7684\u6027\u8d28\u4e3a
\uff08A\uff09\u80fd\u53d1\u751f\u916f\u5316\u53cd\u5e94 (B)\u6613\u6eb6\u4e8e\u6c34\u3001\u9187
(C)\u5177\u6709\u6297\u6c27\u5316\u6027 (D)\u5177\u6709\u5f3a\u9178\u6027
10\uff0e\u7eb3\u7c73\u6750\u6599\u7684\u8868\u9762\u5fae\u7c92\u6570\u5360\u5fae\u7c92\u603b\u6570\u7684\u6bd4\u4f8b\u6781\u5927\uff0c\u8fd9\u662f\u5b83\u6709\u8bb8\u591a\u7279\u6b8a\u6027\u8d28\u7684\u539f\u56e0\uff0c\u5047\u8bbe\u67d0\u787c\u9541\u5316\u5408\u7269\u7684\u7ed3\u6784\u5982\u56fe\u6240\u793a\uff0c\u5219\u8fd9\u79cd\u7eb3\u7c73\u9897\u7c92\u7684\u8868\u9762\u5fae\u7c92\u6570\u5360\u603b\u5fae\u7c92\u6570\u7684\u767e\u5206\u6570\u4e3a
\uff08A\uff0922\uff05 \uff08B\uff09 70\uff05 \uff08C\uff0966.7\uff05 \uff08D\uff09 33.3\uff05
\u4e8c\uff0e\u9009\u62e9\u9898\uff08\u672c\u9898\u5305\u62ec8\u5c0f\u9898\uff0c\u6bcf\u5c0f\u98984\u5206\uff0c\u517132\u5206\u3002\u6bcf\u5c0f\u9898\u67091~2\u4e2a\u9009\u9879\u7b26\u5408\u9898\u610f\u3002\u82e5\u6709\u4e24\u4e2a\u6b63\u786e\u9009\u9879\uff0c\u53ea\u9009\u4e00\u4e2a\u4e14\u6b63\u786e\u7684\u7ed92\u5206\uff0c\u591a\u9009\u3001\u9519\u9009\u90fd\u7ed90\u5206\uff09
11. \u666e\u62c9\u897f\u5766\uff08\u5982\u53f3\u56fe\uff09\u662f\u4e00\u79cd\u80fd\u6539\u5584\u8bb0\u5fc6\u3001\u6297\u5065\u5fd8\u7684\u4e2d\u67a2\u795e\u7ecf\u836f\u3002
\u4e0b\u5217\u5173\u4e8e\u666e\u62c9\u897f\u5766\u7684\u8bf4\u6cd5\u6b63\u786e\u7684\u662f
\uff08A.\uff09\u4e00\u6c2f\u53d6\u4ee3\u7269\u53ea\u67095\u79cd\u3000\u3000\u3000
\uff08B\uff09\u4e8c\u6c27\u53d6\u4ee3\u7269\u53ea\u67095\u79cd
\uff08C\uff09\u53ef\u53d1\u751f\u6c34\u89e3\u53cd\u5e94\u3000\u3000\u3000\u3000\u3000
\uff08D\uff09\u4e0e2-\u6c28\u57fa\u73af\u4e01\u4e8c\u70ef\u4e19\u9178\u4e92\u4e3a\u540c\u5206\u5f02\u6784\u4f53
12\uff0e\u6e29\u5ea6\u4e3aT\u2103\uff0c\u538b\u5f3a\u4e3a1.01\u00d7106Pa\u6761\u4ef6\u4e0b\uff0c\u67d0\u5bc6\u95ed\u5bb9\u5668\u5185\uff0c\u4e0b\u5217\u53cd\u5e94\u8fbe\u5230\u5316\u5b66\u5e73\u8861
A(g)+ B(g) 3C \uff0c\u6d4b\u5f97\u6b64\u65f6c(A)=0.022 mol•L-1\uff1b\u538b\u7f29\u5bb9\u5668\u4f7f\u538b\u5f3a\u589e\u5927\u52302.02\u00d7106Pa\uff0c\u7b2c\u4e8c\u6b21\u8fbe\u5230\u5e73\u8861\u65f6\uff0c\u6d4b\u5f97c(A)=0.05 mol•L-1\uff1b\u82e5\u7ee7\u7eed\u538b\u7f29\u5bb9\u5668\uff0c\u4f7f\u538b\u5f3a\u589e\u5927\u52304.04\u00d7107Pa\uff0c\u7b2c\u4e09\u6b21\u8fbe\u5230\u5e73\u8861\u65f6\uff0c\u6d4b\u5f97c(A)=0.75 mol•L-1\uff1b\u5219\u4e0b\u5217\u5173\u4e8eC\u7269\u8d28\u72b6\u6001\u7684\u63a8\u6d4b\u6b63\u786e\u7684\u662f
\uff08A\uff09C\u4e3a\u975e\u6c14\u6001 \uff08B\uff09C\u4e3a\u6c14\u6001
\uff08C\uff09\u7b2c\u4e8c\u6b21\u8fbe\u5230\u5e73\u8861\u65f6C\u4e3a\u6c14\u6001 \uff08D\uff09\u7b2c\u4e09\u6b21\u8fbe\u5230\u5e73\u8861\u65f6C\u4e3a\u975e\u6c14\u6001
13\uff0e\u53d6\u7b49\u8d28\u91cf\u7684\u5355\u8d28A\u548c\u5316\u5408\u7269B\u4e24\u79cd\u56fa\u4f53\uff0c\u5206\u522b\u6295\u5165\u8db3\u91cf\u7684\u6c34\u4e2d\uff0c\u4ea7\u751fC\u3001D\u4e24\u79cd\u6c14\u4f53\u3002\u4e00\u5b9a\u6761\u4ef6\u4e0b\uff0cC\u548cD\u6070\u597d\u53ef\u5b8c\u5168\u53cd\u5e94\uff0c\u5219\u4e0b\u5217\u53d9\u8ff0\u4e2d\u6b63\u786e\u7684\u662f
\uff08A\uff091 molA\u548c1 molB\u7684\u8d28\u91cf\u76f8\u540c
\uff08B\uff091 molA\u548c1 molB\u4e2d\u6240\u542b\u7684\u8d28\u5b50\u6570\u76f8\u540c
\uff08C\uff091molA\u548c1/2molB\u6240\u542b\u7684\u7535\u5b50\u6570\u76f8\u540c
\uff08D\uff091/2molA\u548c1molB\u4e2d\u6240\u542b\u7684\u4e2d\u5b50\u6570\u76f8\u540c
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\uff08A\uff0928.06g \uff08B\uff0921.66g \uff08C\uff09 10.83g \uff08D\uff091.60g
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(A) 4AlI3+3O2==2Al2O3+6I2 (B) I2+2Ag++2e-=2AgI
(C) Ag\uff0de-=Ag+ (D) I2+2Rb++2e-=2RbI
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(A) \u7532\u9178\u84b8\u6c14\u7684\u5bc6\u5ea6\u5728373K\u65f6\u4e3a1.335g•L-1,\u5728293K\u65f6\u4e3a2.5 g•L-1
(B) \u6c28\u5206\u5b50\u4e0e\u6c34\u5206\u5b50\u5f62\u6210\u4e00\u6c34\u5408\u6c28
(C) \u4e19\u916e\u5728\u5df1\u70f7\u548c\u4e09\u6c1f\u7532\u70f7\u4e2d\u6613\u6eb6\u89e3\uff0c\u5176\u4e2d\u5728\u4e09\u6c1f\u7532\u70f7\u4e2d\u6eb6\u89e3\u65f6\u7684\u70ed\u6548\u5e94\u8f83\u5927
(D) SbH3\u7684\u6cb8\u70b9\u6bd4PH3\u9ad8
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\uff08A\uff09 \uff08B\uff09 \uff08C\uff09 (D)
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21\uff0e\uff086\u5206\uff09
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(1)\u7531\u4e8e\u76d0\u9178\u53d7\u70ed\u84b8\u53d1\u51faHCl\u6c14\u4f53\u6240\u81f4,\u968f\u7740\u53cd\u5e94\u7684\u8fdb\u884c,\u76d0\u9178\u9010\u6e10\u4e0e\u7164\u77f8\u77f3\u4e2d\u7684\u7269\u8d28\u53cd\u5e94\u800c\u88ab\u6d88\u8017\uff0c\u56e0\u6b64\uff0c\u6392\u6c14\u7684pH\u4ece\u5c0f\u9010\u6e10\u53d8\u5927\uff0c\u5982\u679c\u6392\u6c14\u7ba1\u52a0\u957f\u4e00\u500d\uff0c\u610f\u5473\u7740\u6392\u6c14\u88ab\u51b7\u5374\u7684\u7a0b\u5ea6\u66f4\u9ad8\uff0cHCl\u66f4\u591a\u88ab\u51b7\u51dd\u56de\u6d41,\u6545\u6392\u6c14\u7684pH\u6709\u6240\u589e\u5927\u3002\uff083\u5206\uff09
(2)\u7164\u77f8\u77f3\u4e2d\u7684\u94c1\u7684\u6c27\u5316\u7269\u6709Fe2O3\u548cFeO,\u4e0e\u9178\u53cd\u5e94\u9996\u5148\u751f\u6210\u8f83\u591a\u7684\u662f\u4e8c\u4ef7\u94c1\u76d0,\u6545\u5448\u9ec4\u7eff\u8272\uff1b\u7531\u4e8eFe2O3\u9010\u6e10\u6eb6\u51fa\uff0c\u52a0\u4e4bFe2+\u88ab\u6c27\u5316\u4e3aFe3+\uff0c\u81f4\u4f7f\u6eb6\u6db2\u4e2dFe2+\u6d53\u5ea6\u9010\u6e10\u964d\u4f4e\uff0cFe3+\u6d53\u5ea6\u5347\u9ad8\uff0c\u5e76\u6709\u90e8\u5206Fe3+\u6c34\u89e3\uff0c\u989c\u8272\u5448\u6240\u8ff0\u53d8\u5316\u3002\uff083\u5206\uff09
\uff083\uff09\u6c89\u6dc0\u7269\u662f\u6c34\u5408\u786b\u9178\u9499\uff08\u6216\u786b\u9178\u9499\uff09\uff0c\u7531\u4e8e\u786b\u9178\u9499\u662f\u5fae\u6eb6\u7684\uff0c\u5728\u7a00BAC\u6eb6\u6db2\u4e2d\u8fbe\u5230\u9971\u548c\uff0c\u6d53\u7f29\u84b8\u53d1\u8fc7\u7a0b\u4e2d\u53d8\u4e3a\u8fc7\u9971\u548c\uff0c\u6545\u5f62\u6210\u7ec6\u6676\u72b6\u6790\u51fa\u3002\uff083\u5206\uff09
\u4e94\uff0e\uff08\u672c\u9898\u5305\u62ec2\u4e2a\u5c0f\u9898\uff0c\u517115\u5206\uff09
24\uff0e\uff087\u5206\uff09
\uff081\uff09\u4e59\u57fa \uff1bC9H12O4\uff1b \uff1b\u916f\u7c7b
\uff082\uff09\u24608\u79cd \uff1b3\u4e2a\uff1b 1\u4e2a\uff1b \u2461 D \uff08\u6bcf\u7a7a1\u5206\uff09
25.\uff088\u5206\uff09
(1)A B. C.
\uff082\u5206\uff09 \uff082\u5206\uff09 \uff082\u5206\uff09
(2)
\u7b49\u3002
\uff081\u5206\uff09 \uff081\u5206\uff09
\uff08\u5176\u4f59\u591a\u5206\u5b50\u81ea\u805a\u7684\u4ea7\u7269\uff0c\u53ea\u8981\u7ed3\u6784\u5408\u7406\u4e5f\u7ed9\u5206\uff09
\u516d\uff0e\uff08\u672c\u9898\u5305\u62ec2\u4e2a\u5c0f\u9898\uff0c\u517124\u5206\uff09
26\u3001\uff0811\u5206\uff09
\uff081\uff09Cu2S+2MnO4- +8H+==2Cu2+ + SO42-+ 2Mn2+ + 4H2O \uff082\u5206\uff09
5CuS+8MnO4- +24H+==5Cu2+ + 5SO42- + 8Mn2+ + 12H2O \uff082\u5206\uff09
5Fe2+ + MnO4- +8H+ === 5Fe3+ + Mn2+ + 4H2O \uff082\u5206\uff09
(2) \u8bbe Cu2S Xmol CuS Ymol
160X + 96Y == 10
\uff083\u5206\uff09
X=0.02125 Y=0.06875 W=66% \uff082\u5206\uff09
27\uff0e\uff0813\u5206\uff09
(1)\u300066.5\u3000 (2\u5206)
(2) \u8981\u70b9\u4e4b\u4e00\uff1aD\u4e2d\u6240\u542b\u7684\u53e6\u4e00\u79cd\u5143\u7d20\u7684\u603b\u5f0f\u91cf\u4e3a\uff1a66.5\u00d7(1-0.4211-0.5338)=3,\u5143\u7d20\u7684\u76f8\u5bf9\u539f\u5b50\u8d28\u91cf\u6bd43\u5c0f\u7684\u552f\u6709H\u5143\u7d20\uff0c\u6545D\u5206\u5b50\u4e2d\u5fc5\u67093\u4e2a\u6c22\u539f\u5b50\u3002 (2\u5206)
\u8981\u70b9\u4e4b\u4e8c\uff1a\u636e\u8981\u70b9\u4e4b\u4e00\uff0c\u63a8\u5b9aE\u4e3a\u6c22\u5316\u7269\uff0c\u8bbe\u5176\u5206\u5b50\u5f0f\u4e3aXHn ,X\u7684\u76f8\u5bf9\u539f\u5b50\u8d28\u91cf\u4e3aa,\u5219\uff1a
\uff0ca=7n\uff0c\u7ecf\u8ba8\u8bba\uff0c\u5f53n=4\uff0ca=28\u65f6\u7b26\u5408\u9898\u610f\u3002\u56e0\u6b64X\u4e3aSi
\uff083\u5206\uff09
\u8981\u70b9\u4e4b\u4e09\uff1a\u636e\u8981\u70b9\u4e00\u4e0e\u8981\u70b9\u4e8c\u53ef\u7acb\u5373\u5047\u8bbeD\u4e3aSiH3Y\u3002 (1\u5206)
\u8981\u70b9\u4e4b\u56db\uff1a\u8bbeY\u7684\u76f8\u5bf9\u539f\u5b50\u8d28\u91cf\u4e3ab,\u636e \u3000\u3000\u5f97b=35.5\uff0c\u6545Y\u662fCl (2\u5206)
\u8981\u70b9\u4e4b\u4e94\uff1a\u7531F\u4e2dX\u3001Y\u7684\u8d28\u91cf\u5206\u6570\uff0c\u53ef\u6c42\u5f97\u5176\u6700\u7b80\u5f0f\u4e3aSiCl3\uff0c\u4ece\u4ef7\u6001\u4e0d\u96be\u5f97\u51faF\u7684\u5206\u5b50\u5f0f\u4e3aSi2Cl6\uff082\u5206\uff09
\u56e0\u6b64\u5404\u7269\u8d28\u5206\u522b\u4e3a\uff1aA.SiCl4\uff1b B.SiHCl3\uff1b C.SiH2Cl2\uff1b D.SiH3Cl\uff1b E.SiH4\uff1b F.Si2Cl6
\uff081\u5206\uff09
故答案为：C9H12O4；酯；
（2）由题意可知分子中有几种类型的氢原子就会出现几个峰，图乙中共7个峰，属于有7种化学环境不同的氢原子；化学环境相同的氢原子越多，峰线的强度（高度）越大，化学环境相同的氢原子为-CH3上的H，共3个，谱线最低者表示有1个H，
故答案为：7；3；1．
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