已知有机物A、B、C、D、E、F有以下转化关系．A是最简单的烯烃；E是不溶于水且具有香味的无色液体，相对分

\u5df2\u77e5\u6709\u673a\u7269A\u3001B\u3001C\u3001D\u3001E\u3001F\u6709\u4ee5\u4e0b\u8f6c\u5316\u5173\u7cfb\u3002A\u4e3a\u6c14\u6001\u70c3\uff0c\u6807\u51b5\u4e0b\u7684\u5bc6\u5ea6\u4e3a1.25g/L\uff1bE\u662f\u4e0d\u6eb6\u4e8e\u6c34\u4e14\u5177\u6709\u9999\u5473

\uff0814\u5206\uff09\uff081\uff09CH 3 CHO (2) \u7f9f\u57fa \u7fa7\u57fa\uff083\uff09\u24612CH 3 CH 2 OH +O 2 2CH 3 CHO + 2H 2 O \u2463CH 3 COOH+C 2 H 5 OH CH 3 COOC 2 H 5 +H 2 O\uff084\uff09CH 3 CHO+2Cu(OH) 2 +NaOH CH 3 COONa+3H 2 O+Cu 2 O\u2193\uff085\uff09\u9178\u6027\u9ad8\u9530\u9178\u94be\u6216\u9178\u6027\u91cd\u94ec\u9178\u94be\uff086\uff09 \u8bd5\u9898\u5206\u6790\uff1aA\u4e3a\u6c14\u6001\u70c3\uff0c\u6807\u51b5\u4e0b\u7684\u5bc6\u5ea6\u4e3a1.25g/L\uff0c\u5219A\u7684\u76f8\u5bf9\u5206\u5b50\u8d28\u91cf\u662f1.25\u00d722.4\uff1d28\uff0c\u6240\u4ee5A\u662f\u4e59\u70ef\u3002\u4e59\u70ef\u548c\u6c34\u53d1\u751f\u52a0\u6210\u53cd\u5e94\u751f\u6210\u4e59\u9187\uff0c\u5373B\u662f\u4e59\u9187\u3002\u4e59\u9187\u53d1\u751f\u50ac\u5316\u6c27\u5316\u751f\u6210C\uff0c\u5219C\u662f\u4e59\u919b\u3002\u4e59\u9187\u76f4\u63a5\u88ab\u6c27\u5316\u751f\u6210\u4e59\u9178\uff0c\u5373D\u662f\u4e59\u9178\uff0c\u4e59\u9187\u548c\u4e59\u9178\u53d1\u751f\u916f\u5316\u53cd\u5e94\u751f\u6210\u4e59\u9178\u4e59\u916f\uff0c\u5373E\u662f\u4e59\u9178\u4e59\u916f\u3002\u4e59\u70ef\u542b\u6709\u78b3\u78b3\u53cc\u952e\uff0c\u80fd\u53d1\u751f\u52a0\u805a\u53cd\u5e94\u751f\u6210\u805a\u4e59\u70ef\uff0c\u5373F\u662f\u805a\u4e59\u70ef\u3002\uff081\uff09\u4e59\u919b\u7684\u7ed3\u6784\u7b80\u5f0f\u662fCH 3 CHO\u3002\uff082\uff09\u4e59\u9187\u4e2d\u542b\u6709\u7684\u5b98\u80fd\u56e2\u662f\u7f9f\u57fa\uff0c\u4e59\u9178\u4e2d\u542b\u6709\u7684\u5b98\u80fd\u56e2\u662f\u7fa7\u57fa\u3002\uff083\uff09\u53cd\u5e94\u2461\u662f\u4e59\u9187\u7684\u50ac\u5316\u6c27\u5316\uff0c\u53cd\u5e94\u7684\u5316\u5b66\u65b9\u7a0b\u5f0f\u662f2CH 3 CH 2 OH +O 2 2CH 3 CHO + 2H 2 O\u3002\u53cd\u5e94\u2463\u662f\u916f\u5316\u53cd\u5e94\uff0c\u65b9\u7a0b\u5f0f\u662fCH 3 COOH+C 2 H 5 OH CH 3 COOC 2 H 5 +H 2 O\u3002\uff084\uff09\u4e59\u919b\u80fd\u88ab\u65b0\u5236\u6c22\u6c27\u5316\u94dc\u60ac\u6d4a\u6db2\u6c27\u5316\uff0c\u53cd\u5e94\u7684\u5316\u5b66\u65b9\u7a0b\u5f0f\u662fCH 3 CHO+2Cu(OH) 2 +NaOH CH 3 COONa+3H 2 O+Cu 2 O\u2193\u3002\uff085\uff09\u9178\u6027\u9ad8\u9530\u9178\u94be\u6216\u9178\u6027\u91cd\u94ec\u9178\u94be\u90fd\u5177\u6709\u5f3a\u6c27\u5316\u6027\uff0c\u53ef\u4ee5\u76f4\u63a5\u5c06\u4e59\u9187\u6c27\u5316\u751f\u6210\u4e59\u9178\u3002\uff086\uff09\u5728\u50ac\u5316\u5242\u90fd\u4f5c\u7528\u4e0b\uff0c\u7532\u82ef\u4e0e\u6d53\u785d\u9178\u548c\u7a00\u786b\u9178\u7684\u6df7\u5408\u6db2\u53d1\u751f\u785d\u5316\u53cd\u5e94\u751f\u6210TNT\uff0c\u53cd\u5e94\u7684\u65b9\u7a0b\u5f0f\u662f \u3002\u70b9\u8bc4\uff1a\u8be5\u9898\u662f\u57fa\u7840\u6027\u8bd5\u9898\u7684\u8003\u67e5\uff0c\u6d89\u53ca\u70ef\u3001\u9187\u3001\u916f\u7b49\u6027\u8d28\u4e0e\u8f6c\u5316\uff0c\u96be\u5ea6\u4e0d\u5927\uff0c\u662f\u5bf9\u6709\u673a\u77e5\u8bc6\u7684\u7efc\u5408\u8fd0\u7528\u3002\u6709\u673a\u63a8\u65ad\u662f\u9ad8\u8003\u4e2d\u7684\u5e38\u89c1\u9898\u578b\uff0c\u6bcf\u5e74\u9ad8\u8003\u4e2d\u5fc5\u8003\uff0c\u7ecf\u5e38\u7ed9\u51fa\u67d0\u53cd\u5e94\u4fe1\u606f\u8981\u6c42\u5b66\u751f\u52a0\u4ee5\u5e94\u7528\uff0c\u80fd\u8f83\u597d\u7684\u8003\u67e5\u8003\u751f\u7684\u9605\u8bfb\u3001\u81ea\u5b66\u80fd\u529b\u548c\u601d\u7ef4\u80fd\u529b\uff0c\u662f\u70ed\u70b9\u9898\u578b\uff0c\u9700\u8981\u91cd\u70b9\u638c\u63e1\u3002\u8be5\u9898\u7684\u7a81\u7834\u70b9\u662f\u4e59\u70ef\u3002

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已知有机物A、B、C、D、E、F有以下转化关系．A是最简单的烯烃，则A为CH₂=CH₂，与水发生加成反应生成B为CH₃CH₂OH，B发生催化氧化得到C为CH₃CHO，E是不溶于水且具有香味的无色液体，应属于酯，相对分子质量是C的2倍，则E分子式为C₄H₈O₂，结构简式为CH₃COOCH₂CH₃，可推知D为CH₃COOH，乙烯发生加聚反应得到F为，
（1）由上述分析可知，C的结构简式为：CH₃CHO，
故答案为：CH₃CHO；
（2）由上述分析可知，B为CH₃CH₂OH，含有官能团为羟基，D为CH₃COOH，含有官能团为羧基，
故答案为：羟基；羧基；
（3）反应②的方程式为：2CH₃CH₂OH+O₂

Cu

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