CH4被Cl2取代的五种产物常温常压和标况下的状态 常温常压下0.1molch4与0.5molcl2混合光照，混...
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CH₄+Cl₂\u2192\uff08\u5149\u7167\uff09CH₃Cl\uff08\u6c14\u4f53\uff09+HCl
CH₃Cl+Cl₂\u2192\uff08\u5149\u7167\uff09CH2Cl₂\uff08\u6cb9\u72b6\u7269\uff09+HCl
CH₂Cl₂+Cl₂\u2192\uff08\u5149\u7167\uff09CHCl₃\uff08\u6cb9\u72b6\u7269\uff09+HCl
CHCl₃+Cl₂\u2192\uff08\u5149\u7167\uff09CCl₄=\uff08\u6cb9\u72b6\u7269\uff09+HCl
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绛旓細涓姘敳鐑(CHCL3),甯告俯涓嬫棤鑹查忔槑閲嶈川娑蹭綋锛屾瀬鏄撴尌鍙戯紝鍛宠緵鐢滆屾湁鐗规畩鑺抽姘 鍥涙隘鐢茬兎(CCL4),甯告俯涓嬪瑙備笌鎬х姸:鏃犺壊鏈夌壒鑷殑閫忔槑娑蹭綋锛屾瀬鏄撴尌鍙
绛旓細CHCl3+Cl2--鍏夌収-->CCl4+HCl 鐢熸垚鐗╀簲绉嶄负锛CH3Cl銆丆H2Cl2銆丆HCl3銆丆Cl4銆丠Cl锛屽埆蹇樹簡HCl
绛旓細4銆丆HCl3+ Cl2 = CCl4 + HCl 鍥涙隘鍖栫⒊/鍥涙隘鐢茬兎 鐢茬兎鍜屾隘姘斿彲浠ュ彂鐢熷彇浠ｅ弽搴旓紝浜х敓姘唬鐢茬兎锛堟隘鐢茬兎锛夊拰姘寲姘㈢殑鎬绘柟绋嬪紡涓猴細CH4 + Cl2 鈫 CH3Cl + HCl杩欐槸涓涓吀鍨嬬殑鍙栦唬鍙嶅簲锛屽叾涓敳鐑蜂腑鐨勬阿鍘熷瓙琚隘姘斾腑鐨勬隘鍘熷瓙鍙栦唬锛岀敓鎴愭隘鐢茬兎鍜屾隘鍖栨阿銆傚簲鐢ㄦ柟闈紝姘敳鐑凤紙CH3Cl锛夊叿鏈夊箍娉涚殑鐢ㄩ斿拰搴旂敤锛1...
绛旓細CH4+Cl2鈫掞紙鍏夌収锛塁H3Cl锛堟皵浣擄級+HCl锛汣H3Cl+Cl2鈫掞紙鍏夌収锛塁H2Cl2娌圭姸鐗+HCl锛汣H2Cl2+Cl2鈫掞紙鍏夌収锛塁HCl3锛堟补鐘剁墿锛+HCl锛汣HCl3+Cl2鈫掞紙鍏夌収锛塁Cl4娌圭姸鐗+HCl銆
绛旓細ch4涓巆l2鍦ㄥ厜鐓т笅鍙嶅簲鍙嗐傚彂鐢熷彇浠ｅ弽搴旓紝鐢熸垚涓姘敳鐑枫佷簩姘敳鐑枫佷笁姘敳鐑枫佸洓姘敳鐑风瓑涓嶆憾浜庢按鐨勬补鐘剁墿鍜屾隘鍖栨阿姘斾綋銆傜敳鐑蜂笌姘皵鍦ㄩ潪鍏夌収鏉′欢涓嬩笉鍙嶅簲銆傜敳鐑峰彲浠ュ湪姘皵涓噧鐑х敓鎴愭隘鍖栨阿鍜岀⒊锛屽睘浜庣疆鎹㈠弽搴旓紝鍙嶅簲鏂圭▼寮廲h4+2cl2=(鐐圭噧)4hcl+c銆傜壒鐐 1銆佸弽搴斾笉鑳借繘琛屽埌搴曘傚彲閫嗗弽搴旀棤璁鸿繘琛屽闀挎椂闂达紝...
绛旓細鐢茬兎鍜屾隘姘鍙嶅簲鐨勫洓绉嶅彇浠ｇ墿涓猴細涓姘敳鐑枫佷簩姘敳鐑枫佷笁姘敳鐑枫佸洓姘寲纰炽傚叿浣撴柟绋嬪紡濡備笅锛欳H4+Cl2鈹鈫扖H3CL+HCl CH3Cl+Cl2鈹鈫扖H2Cl2+HCl CH2Cl2+Cl2鈹鈫扖HCl3+HCl CHCl3+Cl2鈹鈫扖Cl4+HCl 鐢茬兎姘寲鐗╂槸鍖呮嫭涓姘敳鐑凤紙姘敳鐑凤級銆佷簩姘敳鐑枫佷笁姘敳鐑凤紙涔熺О姘豢锛夈佸洓姘寲纰冲洓绉嶄骇鍝佺殑鎬荤О锛岀畝绉癈MS銆傜敳鐑锋隘...
绛旓細CH4鍜孋l2鍙嶅簲浼氱敓鎴怌H3Cl,CH2Cl2,CHCl3,CCl4杩4绉嶄骇鐗锛岃繖鏄鐨勶紝鑰屼笖鏄贩鍚堢墿锛屾牴鏈笉濂藉垎绂伙紝璇曟兂Cl2涓嶤H4鍙嶅簲鍙栦唬涓涓狧锛岀敓鎴怌H3Cl锛岄毦閬撲綘浼氳寰楁鏃跺氨鍙戠敓杩欎竴涓弽搴旓紝鍏跺疄鍚屾椂涔熷湪杩涜鐫鍏朵粬鐨勫弽搴旓紝鍙栦唬涓や釜H鐢氳嚦涓変釜H鎴栬4涓兘鏄彲鑳界殑锛屽鏋淐H4鍜Cl2鐨浣撶Н姣旀槸1:4,閭ｄ箞鑲畾閮ㄥ垎鍙樻垚CCl4,...
绛旓細2 CH4 ~ CHCl3 ~ 3HCl 1 1 3 CH4 ~ CCl4 ~ 4HCl 1 1 4 鍏卞緱鍒癏Cl 10mol锛屽叾涓隘鍘熷瓙10mol 浜х墿CH3Cl銆丆H2Cl2銆丆HCl3銆丆Cl4涓隘鍘熷瓙鍏 10mol 鏁呭叏閮ㄤ骇鐗╀腑鏈20mol姘師瀛愶紝鍙帹鏂湁10mol姘皵鍙傚姞鍙嶅簲銆
绛旓細鐢茬兎涓庢隘姘斿湪鍏夌収涓嬪弽搴斿彲浠ョ敓鎴愪竴姘敳鐑枫佷簩姘敳鐑枫佷笁姘敳鐑銆佸洓姘寲纰筹紝鍙﹀杩樼敓鎴愭隘鍖栨阿銆傛墍浠ユ渶澶氬彲寰楀埌浜旂浜х墿銆傚弽搴斿寲瀛︽柟绋嬪紡涓猴細CH4 + Cl2---鍏夌収鈫扖H3Cl + HCl CH3Cl + Cl2---鍏夌収鈫扖H2Cl2 + HCl CH2Cl2 + Cl2---鍏夌収鈫扖HCl3 + HCl CHCl3 + Cl2---鍏夌収鈫扖Cl4 + HCl ...
绛旓細Cl2鈫掞紙鍏夌収锛塁l*+Cl 2銆侀摼澧為暱闃舵 绗竴姝,CL*(姘嚜鐢卞熀)+CH4=CH3*锛堢敳鍩鸿嚜鐢卞熀锛+HCL 绗簩姝H3*+CL2=CH3Cl+CL 鏂扮敓鎴愮殑姘嚜鐢卞熀鍐嶉噸澶嶇涓姝,杩欐牱鍙嶅 鐞嗚涓婃隘姘旇秺澶,鐢熸垚鐨勫姘唬鐗╄秺澶.褰撴隘姘旇冻澶熷鏃讹紝CH4涓婄殑H鍘熷瓙鍙互鍏ㄩ儴琚彇浠銆3銆侀摼缁堟锛屼袱涓嚜鐢卞熀缁撳悎褰㈡垚鍒嗗瓙.鍙嶅簲鐨...
