已知有机物A、B、C、D、E、F有以下转化关系。A的产量是衡量一个国家石油化工生产水平的标志；D能使石蕊试
\u5df2\u77e5A\u3001B\u3001F\u662f\u5bb6\u5ead\u4e2d\u5e38\u89c1\u7684\u6709\u673a\u7269,E\u7684\u4ea7\u91cf\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u4e2a\u56fd\u5bb6\u77f3\u6cb9\u5316\u5de5\u53d1\u5c55\u7684\u6807\u5fd7A\uff1a\u4e59\u9178
B\uff1a\u4e59\u9187
C\uff1a\u4e59\u9178\u4e59\u916f
D\uff1a\u4e59\u9178\u94a0
E\uff1a\u4e59\u70ef
F\uff1a\u805a\u4e59\u70ef
A \uff1aCH3COOCH2CH3\uff0cD\uff1a\u918b\u9178\uff0c\uff082\uff09\u7f9f\u57fa\uff0c\u6d88\u6bd2\u3001\u71c3\u6599\uff083\uff09CH3CH2OH------CH2=CH2
CH3CHO-------(\u9ad8\u9530\u9178\u94be)CH3COOH,\u6c27\u5316
| （13分）⑴①CH 2 =CH 2 ；CH 3 CHO ；②羟基；羧基 ；③2CH 3 CH 2 OH +O 2 2CH 3 CHO +2H 2 O ⑵d ⑶① ②NaOH溶液 ；Br 2 + 2NaOH=NaBr+NaBrO+H 2 O；分液漏斗 绛旓細宸茬煡鏈夋満鐗〢銆丅銆C銆D銆丒銆丗鏈変互涓嬭浆鍖栧叧绯伙紟A鏄渶绠鍗曠殑鐑儍锛屽垯A涓篊H2=CH2锛屼笌姘村彂鐢熷姞鎴愬弽搴旂敓鎴怋涓篊H3CH2OH锛孊鍙戠敓鍌寲姘у寲寰楀埌C涓篊H3CHO锛孍鏄笉婧朵簬姘翠笖鍏锋湁棣欏懗鐨勬棤鑹叉恫浣擄紝搴斿睘浜庨叝锛岀浉瀵瑰垎瀛愯川閲忔槸C鐨2鍊嶏紝鍒橢鍒嗗瓙寮忎负C4H8O2锛岀粨鏋勭畝寮忎负CH3COOCH2CH3锛屽彲鎺ㄧ煡D涓篊H3COOH锛屼箼鐑彂鐢熷姞鑱... 绛旓細E鐨勫垎瀛愬紡涓篊5H10O2锛孍涓烘棤鏀摼鐨勫寲鍚鐗╋紝骞朵笖鍚湁5涓狢鍘熷瓙锛岀敱C鍜孌鍙嶅簲鐢熸垚锛孋鑳藉拰纰抽吀姘㈤挔鍙嶅簲锛屽垯C涓虹晶閰锛孌涓洪唶锛屼簩鑰呭叡鍚5涓狢鍘熷瓙锛屽苟涓擟鍜孌鐨勭浉瀵瑰垎瀛愯川閲忕浉绛夛紝鍒機涓轰箼閰搞丏涓轰笝閱囷紝E鏃犳敮閾撅紝D搴斾负1-涓欓唶锛屼簩鑰呭彂鐢熼叝鍖栧弽搴旂敓鎴愰叝E锛鍒橢涓篊H3COOCH2CH2CH3锛汚鏄敱B涓庝箼閰搞佷笝閱囧彂鐢... 绛旓細(1) 锛涘彇浠ｅ弽搴(2) 锛涚⒊纰冲弻閿侀啗鍩恒侀厷缇熷熀锛堟垨纰崇⒊鍙岄敭銆侀啗鍩恒佺緹鍩猴級(3) 绛旓細锛3锛C涓篈 锛 涓嶩Cl鍔犳垚鐨勪骇鐗╋紝鍥犱负鍚庨潰鐨勪骇鐗〧鍚湁鍏厓鐜紝鎵浠l杩炴帴鍦ㄤ笌缇у熀鐩歌繛鐨凜鍘熷瓙涓婏紝缁撴瀯绠寮忎负锛 C缁忔按瑙ｃ侀吀鍖栧悗寰楀埌E锛2鍒嗗瓙E涔嬮棿鍙戠敓閰寲鍙嶅簲鍙緱F锛 锛4锛堿涓惈鏈夌晶鍩猴紝鑳戒笌NaHCO 3 婧舵恫鍙嶅簲鐢熸垚缇ч吀鐩愩丆O 2 鍜屾按銆 绛旓細鍥炵瓟锛(1)缇熷熀 (2)鍔犳垚鍙嶅簲 (3)鈶♀憿鈶 (4) (5)CH 2 BrCH 2 Br + 2NaOH鈫扖H CH + 2NaBr +2H 2 O 绛旓細鐢辨鍥捐浆鍖栧叧绯诲強B鐨勭粨鏋勭畝寮忓彲鎺ㄧ煡锛孉鐨勭粨鏋勭畝寮忎负 銆(1)C涓虹敳閰搞侲涓惈鏈夌殑瀹樿兘鍥负锛氣擟HO銆佲擟OO鈥斻鏈夋満鐗〣涓惈鏈夌晶鍩恒佺緹鍩恒佽嫰鐜紝缇у熀銆佺緹鍩哄彲浠ュ彂鐢熼叝鍖栧弽搴旓紝鍗冲彇浠ｅ弽搴旓紝閱囩緹鍩哄彲浠ュ彂鐢熸秷鍘诲弽搴旂敓鎴愮⒊纰冲弻閿紝杩樺彲浠ヨ姘у寲涓洪啗鍩猴紝鑻幆鍙互涓嶩 2 鍦ㄤ竴瀹氭潯浠朵笅鍔犳垚涓虹幆宸辩兎缁撴瀯銆(2)... 绛旓細A CH2=CH2 B CH3CH2OH 涔欓唶 C CH3COOCH2CH3涔欓吀涔欓叝 D CH3COOH涔欓吀 E F CH4 CH3COOH+CH3CH2OH=CH3COOCH2CH3+H2O 绛旓細鐢E鐨勭粨鏋勶紝鍙帹鐭锛孊涓猴紝缁撳悎A鐨勫垎瀛愬紡C12H16O4鍙奀銆丏杞寲涓篎鐨勫弽搴旀潯浠讹紝鍙帹鐭涓轰箼閰锛孌涓轰箼閱囷紝G涓轰箼閱涳紝F涓轰箼閰镐箼閰紱鐢BCD鐨勭粨鏋勶紝缁撳悎A鐨勫垎瀛愬紡鍙夾杞寲涓築CD鐨勫弽搴旀潯浠讹紝鍙帹鍑篈涓猴紝锛1锛夊弽搴斺憽涓轰箼閰镐笌涔欓唶鐨勯叝鍖栧弽搴旓紝涔熶负鍙栦唬鍙嶅簲锛屾晠绛旀涓猴細鍙栦唬锛堥叝鍖栵級鍙嶅簲锛涳紙2锛塂涓轰箼閱... 绛旓細A涓篊H2=CH2锛C涓篊H2BrCH2Br锛汦涓篊H3CHO锛屾晠绛旀涓猴細CH2=CH2锛汣H2BrCH2Br锛汣H3CHO锛涳紙2锛B涓D鍙嶅簲鐢熸垚涔欓吀涔欓叝鐨勫寲瀛︽柟绋嬪紡涓猴細CH3COOH+CH3CH2OHCH3COOC2H5+H2O锛屽睘浜庨叝鍖栧弽搴旓紙鍙栦唬鍙嶅簲锛夛紝鏁呯瓟妗堜负锛欳H3COOH+CH3CH2OHCH3COOC2H5+H2O锛涢叝鍖栧弽搴旓紙鍙栦唬鍙嶅簲锛夛紱锛3锛塂涓篊H3COOH锛屽叿鏈夐吀鐨勯氭э紝瀹冭兘浣跨传鑹茬殑... 绛旓細C鑳借窡NaHCO 3 鍙戠敓鍙嶅簲锛屽垯C搴斾负缇ч吀锛屾牴鎹瓸缁撴瀯涓殑瀹樿兘鍥㈠彲浠ョ湅鍑锛孊鑳藉彂鐢熷姞鎴愩佸彇浠ｃ侀叝鍖栥佹秷鍘汇佺疆鎹㈢瓑鍙嶅簲锛汣鍜孌鐨勭浉瀵瑰垎瀛愯川閲忕浉绛夛紝鐢盓鐨勫垎瀛愬紡鍙煡C鍚湁2涓狢鍘熷瓙锛屽簲涓篊H 3 COOH锛孌涓哄惈鏈3涓狢鍘熷瓙鐨勯唶锛屼笖D缁忓偓鍖栨哀鍖栧悗鐨勪骇鐗╀笉鑳藉彂鐢熼摱闀滃弽搴旓紝鍙煡D搴斾负 锛屽垯A涓 锛孍涓篊H 3 ... 本站交流只代表网友个人观点，与本站立场无关 |
