A~J均为有机化合物，它们之间的转化如下图所示： 实验表明： ①D既能发生银镜反应，又能与 A～J均为有机化合物，它们之间的转化如图所示：实验表明：①D...
A\uff5eJ\u5747\u4e3a\u6709\u673a\u5316\u5408\u7269\uff0c\u5b83\u4eec\u4e4b\u95f4\u7684\u8f6c\u5316\u5982\u4e0b\u56fe\u6240\u793a\uff1a \u5b9e\u9a8c\u8bc1\u660e: \u2460D\u65e2\u80fd\u53d1\u751f\u94f6\u955c\u53cd\u5e94\uff0c\u53c8\u80fd\u4e0e\u91d1\u5c5e\u94a0A\u2192F\u7684\u8fc7\u7a0b\u662f\u6bd4\u8f83\u7b80\u5355\u7684\uff0c\u90fd\u662f\u5e38\u89c4\u53cd\u5e94
A\u3001\u75311,3-\u4e01\u4e8c\u70ef\u52a0\u6210Br2\u800c\u6765\uff0c\u52a0\u70ed\u6761\u4ef6\uff0c\u56e0\u6b64\u5e94\u4e3a1,4\u52a0\u6210\u4ea7\u7269\uff0cCH2Br-CH=CH-CH2Br
B\u3001\u78b1\u6027\u6c34\u89e3\uff0cCH2OH-CH=CH-CH2OH
C\u3001\u50ac\u5316\u52a0\u6c22\uff0cCH2OH-CH2-CH2-CH2OH
D\u3001\u50ac\u5316\u6c27\u5316\uff0cCH2OH-CH2-CH2-CHO
E\u3001\u94f6\u955c\u53cd\u5e94\uff0c\u9178\u5316\uff0cCH2OH-CH2-CH2-COOH
F\u3001\u6d53\u786b\u9178\u52a0\u70ed\uff0c\u53d1\u751f\u7684\u662f\u5206\u5b50\u5185\u916f\u5316\u53cd\u5e94
A\u2192J\u7684\u8fc7\u7a0b\u770b\u8d77\u6765\u6bd4\u8f83\u590d\u6742\uff0c\u4f46\u662f\u6293\u4f4f\u7279\u5f81\u6027\u7684\u53cd\u5e94\u6761\u4ef6\u5c31\u4e0d\u96be\u53d1\u73b0\uff1a
G\u2014Cl2/H2O\u2192H\u2014Ca(OH)2\u2192I
\u8fd9\u662f\u975e\u5e38\u6807\u5fd7\u6027\u7684\u53cd\u5e94\u6761\u4ef6\uff0cG\u4e2d\u542b\u6709\u53cc\u952e\uff0c\u901a\u8fc7Cl2/H2O\u751f\u6210\u03b1-\u6c2f\u4ee3\u9187\uff0c\u518d\u7ecfCa(OH)2\u5904\u7406\u751f\u6210\u4e09\u5143\u73af\u919a\u3002
G\u3001\u6d53\u786b\u9178\u52a0\u70ed\uff0c\u5206\u5b50\u5185\u4e24\u4e2a\u7f9f\u57fa\u95f4\u8131\u6c34\uff0c\u751f\u6210\u6c27\u6742\u73af
H\u3001\u751f\u6210\u53cc\u952e\u7ecfCl2\u52a0\u6210\u540e\u6c34\u89e3
I\u3001\u03b1-\u6c2f\u4ee3\u9187\u7ecfCa(OH)2\u5904\u7406\u751f\u6210\u4e09\u5143\u73af\u919a
J\u3001\u6c34\u89e3\uff0c\u4e09\u5143\u73af\u6253\u5f00\uff0c\u751f\u6210\u4e8c\u9187
\u4f9d\u636e\u9898\u7ed9\u4fe1\u606f\u2460\u2461\uff0c\u53ef\u63a8\u77e5\uff0cCH2=CH-CH=CH2\u4e0eBr2\u53d1\u751f\u7684\u662f1\uff0c4-\u52a0\u6210\uff0cA\u4e3aBrCH2CH=CHCH2Br\uff0c\u4f9d\u6b21\u53ef\u5f97B\u4e3aHOCH2CH=CHCH2OH\uff0cC\u4e3aHOCH2CH2CH2CH2OH\uff0cD\u4e3aHOCH2CH2CH2CHO\uff0cE\u4e3aHOCH2CH2CH2COOH\uff0cF\u4e3a\uff0e\u518d\u5206\u6790\u53e6\u4e00\u6761\u7ebf\uff0cB\u2192G\u5e94\u8be5\u662f\u5206\u5b50\u5185\u6210\u919a\uff0cG\u4e3a\uff1bG\u2192H\u5e94\u8be5\u662fG\u4e0eHClO\u53d1\u751f\u52a0\u6210\u53cd\u5e94\uff0cH\u5e94\u8be5\u4e3a\uff1bH\u2192I\u662f\uff1a2+Ca\uff08OH\uff092=2+CaCl2+2H2O\uff1bI\u2192J\u662f\u919a\u7684\u5f00\u73af\uff0c\u4e94\u5143\u73af\u76f8\u5bf9\u4e8e\u4e09\u5143\u73af\u7a33\u5b9a\uff0c\u56e0\u6b64\u53cd\u5e94\u4e3a\uff1a\uff0e\uff081\uff09\u7531\u4e0a\u8ff0\u5206\u6790\u53ef\u77e5\uff0cA\u4e3aBrCH2CH=CHCH2Br\uff1bA\u53d1\u751f\u53d6\u4ee3\u53cd\u5e94\u751f\u6210B\u4e3aHOCH2CH=CHCH2OH\uff0c\u6545\u7b54\u6848\u4e3a\uff1aBrCH2CH=CHCH2Br\uff1b\u53d6\u4ee3\u53cd\u5e94\uff1b\uff082\uff09\u7531\u4e0a\u8ff0\u5206\u6790\u53ef\u77e5\uff0cD\u7684\u7ed3\u6784\u7b80\u5f0fHOCH2CH2CH2CHO\uff0c\u6545\u7b54\u6848\u4e3a\uff1aHOCH2CH2CH2CHO\uff1b\uff083\uff09E\u4e3aHOCH2CH2CH2COOH\uff0cF\u4e3a\uff0cE\u53d1\u751f\u5206\u5b50\u5185\u916f\u5316\u53cd\u5e94\u751f\u6210F\uff0c\u53cd\u5e94\u65b9\u7a0b\u5f0f\u4e3aHOCH2CH2CH2COOH\u6d53H2SO4\u25b3+H2O\uff0eE\u4e2d\u7684\u5b98\u80fd\u56e2\u6709\u7f9f\u57fa\u3001\u7fa7\u57fa\uff0e\u4e0eE\u5177\u6709\u76f8\u540c\u5b98\u80fd\u56e2\u7684E\u7684\u540c\u5206\u5f02\u6784\u4f53\u8fd8\u6709 \uff0c\u6545\u7b54\u6848\u4e3a\uff1aHOCH2CH2CH2COOH\u6d53H2SO4\u25b3+H2O\uff1b\u7f9f\u57fa\u3001\u7fa7\u57fa\uff1b\uff1b\uff084\uff09\u7531\u4e0a\u8ff0\u5206\u6790\u53ef\u77e5\uff0cG\u7684\u7ed3\u6784\u7b80\u5f0f\u4e3a\uff0c\u6545\u7b54\u6848\u4e3a\uff1a\uff1b\uff085\uff09I\u2192J\u662f\u919a\u7684\u5f00\u73af\uff0c\u4e94\u5143\u73af\u76f8\u5bf9\u4e8e\u4e09\u5143\u73af\u7a33\u5b9a\uff0c\u53cd\u5e94\u65b9\u7a0b\u5f0f\uff0c\u6545\u7b54\u6848\u4e3a\uff1a\uff0e
| （1）BrCH 2 CH=CHCH 2 Br；取代（或水解） |
| （2） （3） ；羧基、羟基； 、 、 、 （4） （5） |
绛旓細G涓 锛汫鈫扝搴旇鏄疓涓嶩ClO鍙戠敓鍔犳垚鍙嶅簲锛孒搴旇涓 锛汬鈫扞鏄細2 +Ca锛圤H锛 2 =2 +CaCl 2 +2H 2 O锛汭鈫J鏄啔鐨勫紑鐜紝浜斿厓鐜浉瀵逛簬涓夊厓鐜ǔ瀹氾紝鍥犳鍙嶅簲涓猴細 锛庯紙1锛夌敱涓婅堪鍒嗘瀽鍙煡锛孉涓築rCH 2 CH=CHCH 2 Br锛汚鍙戠敓鍙栦唬鍙嶅簲鐢熸垚B涓篐OCH 2 CH=CHCH 2 OH锛屾晠绛旀涓猴細BrCH 2...
绛旓細I鈫J鏄啔鐨勫紑鐜紝浜斿厓鐜浉瀵逛簬涓夊厓鐜ǔ瀹氾紝鍥犳鍙嶅簲涓猴細锛庯紙1锛夌敱涓婅堪鍒嗘瀽鍙煡锛孉涓築rCH2CH=CHCH2Br锛汚鍙戠敓鍙栦唬鍙嶅簲鐢熸垚B涓篐OCH2CH=CHCH2OH锛屾晠绛旀涓猴細BrCH2CH=CHCH2Br锛涘彇浠ｅ弽搴旓紱锛2锛夌敱涓婅堪鍒嗘瀽鍙煡锛孌鐨勭粨鏋勭畝寮廐OCH2CH2CH2CHO锛屾晠绛旀涓猴細HOCH2CH2CH2CHO锛涳紙3锛塃涓篐OCH2CH2CH2COOH锛孎...
绛旓細锛1锛塀rCH 2 CH锛滳HCH 2 Br 锛涘彇浠ｏ紙鎴栨按瑙ｏ級 锛2锛 锛3锛 锛 缇у熀銆佺緹鍩猴紱 锛堜换鎰忎袱涓級锛4锛 锛5锛
绛旓細J銆佹按瑙ｏ紝涓夊厓鐜墦寮锛岀敓鎴愪簩閱
绛旓細J鍥涙阿鍛嬪杻-2,3-浜岄唶 锛1锛A鐨勭粨鏋勭畝寮忎负___Br鈥擟H2鈥擟H=CH鈥擟H2鈥擝r___锛岀敱A鐢熸垚B鐨勫弽搴旂被鍨嬫槸___姘磋В___鍙嶅簲锛涳紙2锛塂鐨勭粨鏋勭畝寮忎负___HOCH2CH2CH2CHO___;锛3锛夌敱E鐢熸垚F鐨勫寲瀛︽柟绋嬪紡涓篲_HOCH2CH2CH2COOH鈥旀祿纭吀鈫扖4H6O2+H2O___锛孍涓殑瀹樿兘鍥㈡湁___缇у熀鍜屾皵鍟婄緹鍩篲__锛屼笌E鍏...
绛旓細褰撶劧杩樼粨鍚堝叾浠栦俊鎭紝鏈鍚庡緱鍑篏涓猴細甯屾湜鍙互甯埌浣
绛旓細锛1锛塁H 2 =CH-CH=CH 2 鍔犳垚 锛2锛塇OCH 2 CH 2 CH 2 CHO 璇曢鍒嗘瀽锛氱敱淇℃伅鈶犫淴鐨勫垎瀛愮粨鏋勪腑鏃犳敮閾撅紝閾剧姸浜岀儻鐑冣濓紝缁撳悎娴佺▼鍥剧煡X涓惈鏈4涓⒊鍘熷瓙锛屽張鏈夋満鐗涓袱涓⒊纰冲弻閿繛鍦ㄥ悓涓涓⒊鍘熷瓙涓婁笉绋冲畾鎺ㄧ煡X涓篊H 2 =CH-CH=CH 2 锛岀粨鍚堜俊鎭憼鈶℃帹鐭ワ細CH 2 =CH-CH=CH 2 涓嶣...
绛旓細锛1锛1锛2鈥斾簩婧翠箼鐑凤紙1鍒嗭級锛涚緹鍩猴紙1鍒嗭級锛汣 2 H 2 O 4 锛1鍒嗭級锛2锛夊姞鎴愬弽搴旓紱姘у寲鍙嶅簲锛涘彇浠ｅ弽搴旓紙鍚2鍒嗭級锛3锛塁H 2 BrCH 2 Br+2NaOH HOCH 2 CH 2 OH+2NaBr 锛4锛塁H 3 CH=CHCH 3 鐣
绛旓細(1)鍙栦唬鍙嶅簲锛涙按瑙ｅ弽搴旓紱姘у寲鍙嶅簲 (2) (3)7锛 锛 锛
绛旓細G鍜屼箼浜岄唶鍙嶅簲鐢熸垚J锛孞鏄竴绉嶉珮鍒嗗瓙鍖栧悎鐗╋紝鎵浠鐨勭粨鏋勭畝寮忎负锛氾紟锛1锛夐氳繃浠ヤ笂鍒嗘瀽鐭ワ紝B鐨勭粨鏋勭畝寮忎负锛氾紝鏁呯瓟妗堜负锛氾紱锛2锛塎鏄疊鐨勪竴绉嶅悓鍒嗗紓鏋勪綋锛孧鑳戒娇婧寸殑鍥涙隘鍖栫⒊婧舵恫瑜壊锛岃鏄庡惈鏈夌⒊纰冲弻閿紝鍒嗗瓙涓墍鏈夌殑纰冲師瀛愬叡骞抽潰锛屽垯M涓殑纰崇⒊鍙岄敭浣嶄簬涓棿锛岀浉褰撲簬涔欑儻涓殑姘㈠師瀛愯鐢插熀鍙栦唬锛...
